Zirconium-β Zeolite-Catalyzed Continuous-Flow Friedel-Crafts Acylation Reaction

被引：20
|
作者：
Rao, Xiaofeng [1 ]
Ishitani, Haruro [2 ]
Yoo, Woo-Jin [2 ]
Kobayashi, Shu [1 ,2 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
[2] Univ Tokyo, Grad Sch Sci, Green & Sustainable Chem Cooperat Lab, Bunkyo Ku, Tokyo 1130033, Japan
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 8卷 / 03期
基金：
日本学术振兴会; 日本科学技术振兴机构;
关键词：
acylation; zeolites; heterogeneous catalysis; continuous-flow; zirconium; H-BEA ZEOLITE; CHEMISTRY; ACID; OXIDATION; ANISOLE; HYDROGENATION; ALCOHOLS; KETONES; ACETYLATION; ALDEHYDES;
D O I：
10.1002/ajoc.201900012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
H-beta Zeolites, doped with various metal salts, were investigated as heterogeneous catalysts for continuous-flow Friedel-Crafts acylation reactions. It was found that Zr-beta zeolites possessed excellent catalyst activity and stability, which enabled its use as a catalyst, up to 5 days, for Friedel-Crafts reactions between various activated arenes and acid anhydrides. Challenging substrates, such as toluene and m-xylene, were also successfully applied for the continuous-flow process.
引用
收藏
页码：316 / 319
页数：4
相关论文
共 50 条
  • [31] Reaction Profiles of High Silica MOR Zeolite Catalyzed Friedel-Crafts Acylation of Anisole Using Acetic Anhydride in Acetic Acid
    Makihara, Makoto
    Aoki, Hisakazu
    Komura, Kenichi
    [J]. CATALYSIS LETTERS, 2018, 148 (10) : 2974 - 2979
  • [32] O-ACYLATION OF KOJIC ACID BY FRIEDEL-CRAFTS REACTION
    GHOSAL, M
    CHAUDHUR.DN
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (02): : 583 - &
  • [33] REGIOSELECTIVE ACYLATION OF STEROID ESTROGEN ANALOGS BY THE FRIEDEL-CRAFTS REACTION
    SHAVVA, AG
    ELISEEV, II
    BUROVA, EB
    KOVALCHUK, SV
    GINDIN, VA
    [J]. ZHURNAL ORGANICHESKOI KHIMII, 1986, 22 (02): : 442 - 443
  • [34] Friedel-Crafts acylation of anisole with hexanoic acid catalyzed by Hβ zeolite-supported tungstophosphoric acid
    Bai, Guoyi
    Zhang, Huanhuan
    Li, Tianyu
    Dong, Huixian
    Han, Jie
    [J]. RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (08) : 5041 - 5048
  • [35] ON THE STUDIES OF THE FRIEDEL-CRAFTS ACYLATION .3. THE REACTION MECHANISM
    YAMASE, Y
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1961, 34 (04) : 484 - 487
  • [36] Application of the catalytic Friedel-Crafts acylation reaction and regioselectivity correlations
    Wilkinson, Mark C.
    Saez, Fabienne
    Hon, Wei Lee
    [J]. SYNLETT, 2006, (07) : 1063 - 1066
  • [37] Mesopore wall-catalyzed Friedel-Crafts acylation of bulky aromatic compounds in MFI zeolite nanosponge
    Kim, Jeong-Chul
    Cho, Kanghee
    Lee, Sungjune
    Ryoo, Ryong
    [J]. CATALYSIS TODAY, 2015, 243 : 103 - 108
  • [38] AROMATIC ACYLATION REDUCTION - AN EFFICIENT FRIEDEL-CRAFTS ALKYLATION REACTION
    JAXACHAMIEC, A
    SHAH, VP
    KRUSE, LI
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (09): : 1705 - 1706
  • [39] Highly selective Friedel-Crafts acylation of 2-methoxynaphthlene catalyzed by H-BEA zeolite
    Casagrande, M
    Storaro, L
    Lenarda, M
    Ganzerla, R
    [J]. APPLIED CATALYSIS A-GENERAL, 2000, 201 (02) : 263 - 270
  • [40] Friedel-Crafts acylation reaction catalyzed by silica supported sulfonic acids: synthetic aspects and limitations
    Piscopo, Calogero Giancarlo
    Maestri, Giovanni
    Paris, Emanuele
    Santacroce, Veronica
    Maggi, Raimondo
    [J]. ARKIVOC, 2015, : 1 - 9
12345