Theoretical study on adsorbate-induced surface stress of iodide monolayer on Au(111) electrode

被引：0
|
作者：
Xie, Rong [1 ]
机构：
[1] Anhui Inst Architecture & Ind, Sch Mat Sci & Chem Engn, Hefei 230022, Peoples R China
来源：
OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS | 2013年 / 7卷 / 7-8期
关键词：
Anion adsorption; Surface stress; Lattice gas model; ADSORPTION; ELECTROCOMPRESSION; ORIGIN;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The statistical thermodynamic theory of adsorbate-induced surface stress of anion adsorption monolayer on Au(111) has been established by using the lattice gas model and considering various components of the adsorbate-adsorbate interaction energies in the adlayer. The adsorbate-induced surface stress and its components due to various intermolecule forces of iodide adions on the Au(111) electrode surface have been calculated. The calculated surface stress of iodide adions on Au(111) approximates the experiment results. Among various components of the adsorbate-adsorbate interaction energies in the adlayer, the substrate -mediated interaction is significant for the adsorbate-induced surface stress, which shows that indirect contribution of the adsorption energy of iodide adions through the substrate-mediated interaction is very important.
引用
收藏
页码：553 / 559
页数：7
相关论文
共 50 条
  • [31] Adsorbate-induced reconstruction of an array of atomic wires: Indium on the Si(553)-Au surface
    Ahn, J. R.
    Kang, P. G.
    Byun, J. H.
    Yeom, H. W.
    PHYSICAL REVIEW B, 2008, 77 (03)
  • [32] ADSORBATE-INDUCED SURFACE STRESS - PHONON ANOMALY AND RECONSTRUCTION ON NI(001) SURFACES
    MULLER, JE
    WUTTIG, M
    IBACH, H
    PHYSICAL REVIEW LETTERS, 1986, 56 (15) : 1583 - 1586
  • [33] ADSORBATE-INDUCED ANGLE AVERAGING OF CU(111) PHOTOEMISSION SPECTRA
    LINDGREN, SA
    WALLDEN, L
    PHYSICAL REVIEW LETTERS, 1979, 43 (06) : 460 - 463
  • [34] Relating the coverage dependence of oxygen adsorption on Au and Pt fcc(111) surfaces through adsorbate-induced surface electronic structure effects
    Miller, Spencer D.
    Kitchin, John R.
    SURFACE SCIENCE, 2009, 603 (05) : 794 - 801
  • [35] Theoretical analysis of adsorbate-induced row-type alignments on the FCC(110) surface
    Yasutani, K
    Kaburagi, M
    Kang, M
    SURFACE REVIEW AND LETTERS, 1999, 6 (05) : 699 - 704
  • [36] Gas adsorbate-induced Au atomic segregation and clustering from Cu(Au)
    Zhang, Lifeng
    Dong, Zejian
    Wang, Shuangbao
    Luo, Langli
    SCIENCE CHINA-MATERIALS, 2021, 64 (05) : 1256 - 1266
  • [37] Adsorbate-induced surface stress, surface strain and surface reconstruction: S on Cu(100) and Ni(100)
    Bradley, M. K.
    Woodruff, D. P.
    Robinson, J.
    SURFACE SCIENCE, 2013, 613 : 21 - 27
  • [38] Theoretical studies on electrocompression of electrodeposited halide monolayer on Au(111) surface
    Wang, XQ
    Chen, R
    Wang, YL
    He, TJ
    Liu, FC
    JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (39): : 7568 - 7576
  • [39] Theoretical study of thiol-induced reconstructions on the Au(111) surface
    Molina, LM
    Hammer, B
    CHEMICAL PHYSICS LETTERS, 2002, 360 (3-4) : 264 - 271
  • [40] THE ADSORBATE-INDUCED LIFTING OF THE PT(100) SURFACE RECONSTRUCTION
    GARDNER, P
    MARTIN, R
    TUSHAUS, M
    BRADSHAW, AM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 190 - COLL
12345