Statistical thermodynamics of polymers near surfaces

被引:74
|
作者
Szleifer, I
机构
关键词
D O I
10.1016/S1359-0294(96)80142-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent developments in molecular theoretical approaches have improved our understanding of experimental observations of the thermodynamic and structural properties of tethered polymer layers, in particular for short to intermediate chain length molecules. The theoretical treatment of surface segregation behavior in thin films of isomeric polymer blends and block copolymers has recently been shown to require the inclusion of the detailed chemical architecture of the chains as well as of the bulk and surface interactions.
引用
收藏
页码:416 / 423
页数:8
相关论文
共 50 条
  • [21] The flow and adsorption of DNA polymers near surfaces
    Larson, RG
    Li, L
    Chopra, M
    Burns, MA
    SLOW DYNAMICS IN COMPLEX SYSTEMS, 2004, 708 : 386 - 389
  • [22] STATISTICAL THERMODYNAMICS OF CONCENTRATED AND DILUTE SOLUTIONS OF POLYMERS IN MIXED SOLVENTS
    YAMAMOTO, M
    WHITE, JL
    MACLEAN, DL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1971, (NSEP): : 84 - &
  • [23] PREDICTIONS OF ADSORPTION ENTHALPY ON GRAPHITIC SURFACES USING STATISTICAL THERMODYNAMICS
    Wemhoff, Aaron P.
    PROCEEDINGS OF THE ASME SUMMER HEAT TRANSFER CONFERENCE - 2013, VOL 1, 2014,
  • [24] Structure and thermodynamics of ssDNA oligomers near hydrophobic and hydrophilic surfaces
    Elder, Robert M.
    Jayaraman, Arthi
    SOFT MATTER, 2013, 9 (48) : 11521 - 11533
  • [25] Interfacial thermodynamics of confined water near molecularly rough surfaces
    Mittal, Jeetain
    Hummer, Gerhard
    FARADAY DISCUSSIONS, 2010, 146 : 341 - 352
  • [26] Ideal polymers near scale-free surfaces
    Hammer, Yosi
    Kantor, Yacov
    PHYSICAL REVIEW E, 2014, 89 (02):
  • [27] The structure of amorphous polymers near surfaces: athermal systems
    Curro, JG
    Weinhold, JD
    McCoy, JD
    Yethiraj, A
    COMPUTATIONAL AND THEORETICAL POLYMER SCIENCE, 1998, 8 (1-2): : 159 - 168
  • [28] Langevin dynamics simulations of polymers near fluctuating surfaces
    Laradji, M
    COMPUTER SIMULATION STUDIES IN CONDENSED-MATTER PHYSICS XIII, 2001, 86 : 205 - 211
  • [29] New statistical mechanical treatment of systems near surfaces .3. Polydisperse linear and branched polymers in an interacting solution
    Chhajer, M
    Gujrati, PD
    JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (23): : 9799 - 9809
  • [30] New statistical mechanical treatment of systems near surfaces .2. Polydisperse linear and branched polymers in an athermal solution
    Chhajer, M
    Gujrati, PD
    JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (19): : 8101 - 8115