Copper-catalyzed N-arylation of amines/amides in poly(ethylene glycol) as recyclable solvent medium

被引:46
|
作者
Chandrasekhar, S [1 ]
Sultana, SS [1 ]
Yaragorla, SR [1 ]
Reddy, NR [1 ]
机构
[1] Indian Inst Chem Technol, Organ Div 1, Hyderabad 500007, Andhra Pradesh, India
来源
SYNTHESIS-STUTTGART | 2006年 / 05期
关键词
N-arylation; copper iodide; poly(ethylene glycol); reusability;
D O I
10.1055/s-2006-926328
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Buchwald N-arylation of amines and amides is achieved efficiently in PEG (400 Daltons) as solvent medium. The solvent and catalyst recyclability is studied. Interestingly amides underwent N-arylation with better yields.
引用
收藏
页码:839 / 842
页数:4
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