A highly active and air-stable ruthenium complex for olefin metathesis

被引：0
|
作者：
Wakamatsu, H [1 ]
Blechert, S [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 05期
关键词：
biaryls; carbene ligands; metathesis; O ligands; ruthenium;
D O I：
10.1002/1521-3773(20020301)41:5<794::AID-ANIE794>3.0.CO;2-B
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bulky binol-based ligand is the key structural feature of the ruthenium complex 1, which displays an unprecedented metathesis activity combined with high stability. For a range of dienes, ring-closing metathesis reactions catalyzed by 1 lead to near quantitative yields of cycloalkenes after a few minutes.
引用
收藏
页码：794 / +
页数：4
相关论文
共 50 条
  • [41] Ruthenium complexes for olefin metathesis.
    Grubbs, RH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U102 - U102
  • [42] Highly active water-soluble olefin metathesis catalyst
    Hong, Soon Hyeok
    Grubbs, Robert H.
    Journal of the American Chemical Society, 2006, 128 (11): : 3508 - 3509
  • [43] Decomposition of Ruthenium Olefin Metathesis Catalyst
    Jawiczuk, Magdalena
    Marczyk, Anna
    Trzaskowski, Bartosz
    CATALYSTS, 2020, 10 (08) : 1 - 56
  • [44] Cationic Ruthenium Complexes in Olefin Metathesis
    Queval, Pierre
    Jahier, Claire
    Basle, Olivier
    Mauduit, Marc
    CURRENT ORGANIC CHEMISTRY, 2013, 17 (22) : 2560 - 2574
  • [45] Decomposition of ruthenium olefin metathesis catalysts
    Hong, Soon Hyeok
    Wenzel, Anna G.
    Salguero, Tina T.
    Day, Michael W.
    Grubbs, Robert H.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) : 7961 - 7968
  • [46] Photoactivation of Ruthenium Olefin Metathesis Initiators
    Ben-Asuly, Amos
    Aharoni, Anna
    Diesendruck, Charles E.
    Vidavsky, Yuval
    Goldberg, Israel
    Straub, Bernd F.
    Lemcoff, N. Gabriel
    ORGANOMETALLICS, 2009, 28 (16) : 4652 - 4655
  • [47] New ruthenium catalysts for olefin metathesis
    不详
    CHEMICAL & ENGINEERING NEWS, 1998, 76 (40) : 41 - 41
  • [48] Olefin metathesis-active ruthenium complexes bearing a nucleophilic carbene ligand
    Huang, JK
    Stevens, ED
    Nolan, SP
    Petersen, JL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) : 2674 - 2678
  • [49] New class of highly active ruthenium carbene complexes for olefin metathesis: Syntheses, structural, mechanistic, and theoretical aspects.
    Holmann, P
    Hansen, SM
    Volland, MAO
    Rominger, F
    Metz, M
    Eisentrager, F
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U894 - U894
  • [50] Highly active, stable, and selective well-defined silica supported Mo imido olefin metathesis catalysts
    Blanc, Frederic
    Thivolle-Cazat, Jean
    Basset, Jean-Marie
    Coperet, Christophe
    Hock, Adam S.
    Tonzetich, Zachary J.
    Schrock, Richard R.
    Journal of the American Chemical Society, 2007, 129 (05): : 1044 - 1045
12345