A highly active and air-stable ruthenium complex for olefin metathesis

被引：0
|
作者：
Wakamatsu, H [1 ]
Blechert, S [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 05期
关键词：
biaryls; carbene ligands; metathesis; O ligands; ruthenium;
D O I：
10.1002/1521-3773(20020301)41:5<794::AID-ANIE794>3.0.CO;2-B
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bulky binol-based ligand is the key structural feature of the ruthenium complex 1, which displays an unprecedented metathesis activity combined with high stability. For a range of dienes, ring-closing metathesis reactions catalyzed by 1 lead to near quantitative yields of cycloalkenes after a few minutes.
引用
收藏
页码：794 / +
页数：4
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