A new binary accelerator system for sulphur vulcanization of natural rubber

被引:0
|
作者
Aprem, AS
Mathew, G
Joseph, K
Mathew, G
Thomas, S
机构
[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India
[2] CMS Coll, Dept Chem, Kottayam, Kerala, India
[3] St Berchmans Coll, Dept Chem, Changanacherry, Kerala, India
来源
KAUTSCHUK GUMMI KUNSTSTOFFE | 1999年 / 52卷 / 09期
关键词
NR; 1-phenyl-2,4-dithiobiuret; 2-(4-morpholinothio)-benzothiazole (MBS); secondary accelerator;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The use of 1-phenyl-2-4-dithiobiuret (DTB) as a secondary accelerator for 2-(4-morpholinathio)-benzothiazole (MBS) has been investigated in NR. It was found that irrespective of the concentration of DTB, all the cure reactions followed first order kinetics. Mechanical properties of the system were analysed for different DTB loading and the strain crystallising nature of NR is not affected by DTB. In order to correlate the observed technological properties with different types of cross-links equilibrium, swelling and thiol treatment were done. Based on processing characteristics, mechanical properties and swelling behavior, the optimum dosage of DTB was found out.
引用
收藏
页码:576 / +
页数:7
相关论文
共 50 条
  • [21] Progress in Rubber Vulcanization Accelerator
    Li Longfei
    Bai Yinna
    Lei Ming
    Liu Li
    PROGRESS IN CHEMISTRY, 2015, 27 (10) : 1500 - 1508
  • [22] Purified refinery sludge as process aid in sulphur vulcanization of natural rubber
    Kuriakose, AP
    Kochi, SKBN
    KAUTSCHUK GUMMI KUNSTSTOFFE, 1999, 52 (12): : 794 - +
  • [23] Purified refinery sludge as process aid in sulphur vulcanization of natural rubber
    Kuriakose, A.P.
    Manjooran, S.K.B.
    KGK-Kautschuk und Gummi Kunststoffe, 1999, 52 (12):
  • [25] Physical, mechanical, and viscoelastic properties of natural rubber vulcanizates cured with new binary accelerator system
    Aprem, AS
    Joseph, K
    Laxminarayanan, R
    Thomas, S
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 87 (14) : 2193 - 2203
  • [26] Sulphur vulcanization of epoxidized natural rubber oxidized carbon fibres composites
    Ibarra, L
    Palma, E
    KAUTSCHUK GUMMI KUNSTSTOFFE, 1999, 52 (05): : 329 - +
  • [27] The Effect of Novel Binary Accelerator System on Properties of Vulcanized Natural Rubber
    Kamoun, Moez
    Nassour, Abdallah
    Michael, Nelles
    ADVANCES IN MATERIALS SCIENCE AND ENGINEERING, 2009, 2009
  • [28] A new secondary accelerator for the sulfur vulcanization of natural rubber latex and its effect on the rheological properties
    Kurien, M
    Claramma, NM
    Kuriakose, AP
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 93 (06) : 2781 - 2789
  • [29] EFFECT OF SULFENAMIDES AND 2-MERCAPTOBENZOTHIAZOLE AS BINARY ACCELERATOR SYSTEMS ON VULCANIZATION OF RUBBER
    BHATTACHARYYA, PS
    SARANGI, AK
    BASU, DK
    CHAUDHURI, AK
    INDIAN JOURNAL OF TECHNOLOGY, 1977, 15 (03): : 119 - 121
  • [30] Insight into vulcanization mechanism of novel binary accelerators for natural rubber
    Shu-yan Yang
    Zhi-xin Jia
    Lan Liu
    Wei-wen Fu
    De-min Jia
    Yuan-fang Luo
    Chinese Journal of Polymer Science, 2014, 32 : 1077 - 1085