Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes Using Silica Sulfuric Acid as Heterogeneous Reusable Catalyst

被引：29
|
作者：
Azarifar, Davood [1 ]
Najminejad, Zohreh [1 ]
Khosravi, Kaveh [1 ]
机构：
[1] Univ Bu Ali Sina, Dept Chem, Hamadan 65178, Iran
来源：
SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 06期
关键词：
Aldehydes; gem-dihydroperoxides; heterogeneous catalyst; ketones; silica sulfuric acid; AQUEOUS HYDROGEN-PEROXIDE; ANTIMALARIAL ACTIVITY; MILD; BISHYDROPEROXIDES; CYCLOHEXYLIDENEBISHYDROPEROXIDE; 1,2,4,5-TETRAOXACYCLOALKANES; CONVERSION; SYSTEM; IODINE;
D O I：
10.1080/00397911.2011.610549
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Silica sulfuric acid (SSA) was found to efficiently catalyze the conversion of aldehydes and ketones directly into the corresponding gem-dihydroperoxides (DHPs) on treatment with aqueous 30% H2O2 at room temperature. Mild reaction conditions, good to excellent yields, short reaction times, low environmental impact, and recyclability of the catalyst are the main advantages of this synthetic method.
引用
收藏
页码：826 / 836
页数：11
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