State of Water in Perfluorosulfonic Ionomer (Nafion) Proton Exchange Membranes

被引：4

作者：

Lu, Z. ^{[1
]}

Polizos, G.

Manias, E.

Macdonald, D. D. ^{[1
]}

机构：

[1] Penn State Univ, Ctr Electrochem Sci & Technol, University Pk, PA 16802 USA

来源：

BATTERIES AND ENERGY TECHNOLOGY (GENERAL) - 217TH ECS MEETING | 2010年 / 28卷 / 30期

关键词：

POLYMER ELECTROLYTE MEMBRANES; DIELECTRIC-RELAXATION; FUEL-CELL; HYDROPHOBIC HYDRATION; AQUEOUS-SOLUTIONS; GLASS-TRANSITION; TRANSPORT; TEMPERATURE; CONDUCTION; MORPHOLOGY;

D O I：

10.1149/1.3505462

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This manuscript reports on the direct identification of four states of water in hydrated Nafion ionomer polymers, including a quantitative measurement of their dynamics, as previously published in the Journal of the Electrochemical Society, 155, B163-B171 (2008). Here, we provide further details on the dynamics of these water states and we underline still-open scientific questions, towards stimulating further fundamental research in the field.

引用

下载

页码：81 / 89

页数：9

共 50 条

[21] Nafion phosphonic acid composite membranes for proton exchange membranes fuel cells
Teixeira, Fatima C.
de Sa, Ana I.
Teixeira, Antonio P. S.
Rangel, C. M.
APPLIED SURFACE SCIENCE, 2019, 487 : 889 - 897
[22] Correlated interfacial water transport and proton conductivity in perfluorosulfonic acid membranes
Ling, Xiao
Bonn, Mischa
Domke, Katrin F.
Parekh, Sapun H.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (18) : 8715 - 8720
[23] A Molecular Dynamic Simulation of Hydrated Proton Transfer in Perfluorosulfonate Ionomer Membranes (Nafion 117)
Sun, Hong
Yu, Mingfu
Li, Zhijie
Almheiri, Saif
JOURNAL OF CHEMISTRY, 2015, 2015
[24] 2H nuclear magnetic resonance study of deuterated water dynamics in perfluorosulfonic acid ionomer Nafion
Han, Jun Hee
Lee, Kyu Won
Lee, Cheol Eui
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2016, 98 : 280 - 282
[25] 1H nuclear magnetic resonance study of hydrated water dynamics in perfluorosulfonic acid ionomer Nafion
Han, Jun Hee
Lee, Kyu Won
Jeon, G. W.
Lee, Cheol Eui
Park, W. K.
Choi, E. H.
APPLIED PHYSICS LETTERS, 2015, 106 (02)
[26] BLENDS OF NAFION AND DOW PERFLUOROSULFONATED IONOMER MEMBRANES
ZALUSKI, C
XU, G
MACROMOLECULES, 1994, 27 (23) : 6750 - 6754
[27] MORPHOLOGY AND ITS RELATIONSHIP TO EFFICIENCY OF NAFION PERFLUOROSULFONIC ACID MEMBRANES
GIERKE, TD
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (03) : C163 - C163
[28] Transport in short side chain perfluorosulfonic acid ionomer membranes
Holdcroft, Steven
Luo, Xiaoyan
Peron, Jennifer
Zhang, Yongming
Shi, Zhiqing
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
[29] Transport properties of Nafion™ composite membranes for proton-exchange membranes fuel cells
Damay, F
Klein, LC
SOLID STATE IONICS, 2003, 162 : 261 - 267
[30] A study of capillary porous structure and sorption properties of Nafion proton-exchange membranes swollen in water
Divisek, J
Eikerling, M
Mazin, V
Schmitz, H
Stimming, U
Volfkovich, YM
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (08) : 2677 - 2683

← 1 2 3 4 5 →