Effect of Arm Exchange on the Liquid-Solid Transition of Dense Suspensions of Star Polymers

被引：9
|
作者：
Puaud, Fanny [1 ]
Nicolai, Taco [1 ]
Benyahia, Lazhar [1 ]
Nicol, Erwan [1 ]
机构：
[1] Univ Maine, LUNAM, Inst Mol Mat Mans, UMR CNRS 6283, F-72085 Le Mans, France
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2013年 / 117卷 / 40期
关键词：
CRYSTALLIZATION;
D O I：
10.1021/jp407487q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Star polymers with dynamic arm exchange are formed in water by self-assembly of amphiphilic diblock copolymers based on poly(ethylene oxide) end capped with a small hydrophobic block. The arm exchange was arrested in situ by photo-cross-linking of the core. The effect of dynamic arm exchange on the osmotic compressibility and viscosity was investigated systematically as a function of the concentration and temperature. The discontinuous liquid-solid transition reported for dense polymeric micelle suspensions was found to be preserved after dynamic arm exchange was arrested in situ. The effect of cross-linking and aggregation number on the liquid-solid transition was investigated.
引用
收藏
页码：12312 / 12318
页数：7
相关论文
共 50 条
  • [31] PHASE TRANSITION LIQUID-SOLID IN RAMAN SPECTRUM
    VARCHMIN, J
    [J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1970, 70 (1-2): : 13 - &
  • [32] Liquid-solid transition in nuclei of protein crystals
    Lomakin, A
    Asherie, N
    Benedek, GB
    [J]. MONTE CARLO METHOD IN THE PHYSICAL SCIENCES, 2003, 690 : 390 - 391
  • [33] Liquid-solid transition in nuclei of protein crystals
    Lomakin, A
    Asherie, N
    Benedek, GB
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (18) : 10254 - 10257
  • [34] Hydrogel microrheology near the liquid-solid transition
    Larsen, Travis
    Schultz, Kelly
    Furst, Eric M.
    [J]. KOREA-AUSTRALIA RHEOLOGY JOURNAL, 2008, 20 (03) : 165 - 173
  • [35] UNUSUAL LIQUID-SOLID TRANSITION EFFECTS IN A METHOXYPENTAMETHYLFLAVAN
    BENBOW, JJ
    WOOD, DJC
    [J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1958, 243 (1235): : 518 - &
  • [36] Transition pathways between solid and liquid states of dense suspensions in transient and oscillatory shear flows
    Heymann, Lutz
    Chen, Xueming
    Aksel, Nuri
    [J]. XVTH INTERNATIONAL CONGRESS ON RHEOLOGY - THE SOCIETY OF RHEOLOGY 80TH ANNUAL MEETING, PTS 1 AND 2, 2008, 1027 : 698 - 700
  • [37] The putative liquid-liquid transition is a liquid-solid transition in atomistic models of water
    Limmer, David T.
    Chandler, David
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2011, 135 (13):
  • [38] Liquid-solid phase transition in a heterogeneous system of solid spheres
    Rudnyak, VY
    Belkin, AA
    [J]. JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS, 1999, 89 (06) : 1086 - 1088
  • [39] Liquid-solid phase transition in a heterogeneous system of solid spheres
    V. Ya. Rudnyak
    A. A. Belkin
    [J]. Journal of Experimental and Theoretical Physics, 1999, 89 : 1086 - 1088
  • [40] Numerical Investigation of Particle Suspensions in a Liquid-Solid Stirred Tank with Baffles
    Wang, Zhijie
    Zhao, Yanlin
    Yao, Jun
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (01) : 914 - 930
12345