Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands

被引：33
|
作者：
Lee, TW [1 ]
Lau, JPK [1 ]
Wong, WT [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
POLYHEDRON | 2004年 / 23卷 / 06期
关键词：
zinc; 1,3-bis(4-pyridyl)propane; 4,4 '-pyridine; polymeric network; X-ray crystallography;
D O I：
10.1016/j.poly.2003.12.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal-coordination polymers, [Zn-2(bpy)(OAc)(4)](n) (1) and [Zn(bpp)(NO3)(2)](n) (2) were prepared by the layering method using Zn(11) ions, bpy and bpp ligands, and structurally characterized by single-crystal X-ray diffraction analyses. Complexes 1 and 2 were both found to be one-dimensional coordination polymers. The periodic length of the chain between two alternate Zn(II) ions in compound I is 26.92 Angstrom which is more than twice the length of compound 2 (26.92 > 11.92 x 2). (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：999 / 1002
页数：4
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