Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

被引：2
|
作者：
Yang, Hongxuan [1 ]
Dong, Wenke [1 ]
Wang, Wencan [1 ]
Li, Tao [1 ]
Zhao, Wanxiang [1 ]
机构：
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2020年 / 52卷 / 19期
基金：
中国国家自然科学基金;
关键词：
isomerization; stereoselectivity; rhodium; alkene; interconversion; DEHYDROGENATIVE BORYLATION; PALLADIUM(II)-CATALYZED ISOMERIZATION; WITTIG REACTION; ALKENES; MONOISOMERIZATION; VINYLARENES; PINACOLBORANE; NANOPARTICLES; EFFICIENT; 1-ALKENES;
D O I：
10.1055/s-0040-1707166
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new efficient method for the synthesis of a high ratio of E-alkenes from E/Zmixtures of alkenes with B(2)pin(2) in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.
引用
收藏
页码：2833 / 2840
页数：8
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