Forced Coordination Modes of 1,2-Cyclohexanedione Dioxime in Uranyl Complexes

被引：4
|
作者：
Beirakhov, A. G. [1 ]
Orlova, I. M. [1 ]
Il'in, E. G. [1 ]
Sakharov, S. G. [1 ]
Churakov, A. V. [1 ]
Gorbunova, Yu. E. [1 ]
Mikhailov, Yu. N. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 12期
关键词：
Coordination Mode; Uranyl Complex; Oxalate Group; Uranyl Compound; Uranyl Nitrate Hexahydrate;
D O I：
10.1134/S0036023608120115
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Unusual coordination modes of 1,2-cyclohexane dionedioxime in uranyl complexes, i.e., tridentate chelating/bridging and (E, Z)-pentadentate chelating/bridging ones, were established by X-ray crystallography of single crystals of (CN(3)H(6))(3)[(UO(2))(2)(C(6)H(9)N(2)O(2))(C(6)H(8)N(2)O(2))(C(2)O(4))(2)] center dot (2)H(2)O and [(UO(2))(2)(C(6)H(8)N(2)O(2))(2)(H(2)O)(3)] center dot (2)H(2)O. The conditions of the emergence of such coordination modes were determined. The possibility of (E/Z) izomerization of alpha-dioximes in reactions of uranyl complexes.
引用
收藏
页码：1898 / 1909
页数：12
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