The synthesis and structural characterization of some triorganothin(IV) complexes of 5-(4-chlorophenylazo)salicylic acid:: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate•0.5C6H14

被引：0

作者：

Baul, TSB

Dhar, S

Kharbani, N

Pyke, SM

Butcher, R

Smith, FE

机构：

[1] NE Hill Univ, Chem Lab, Reg Sophisticated Instrumentat Ctr, Shillong 793003, Meghalaya, India

[2] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[3] Howard Univ, Dept Chem, Washington, DC 20059 USA

[4] Laurentian Univ, Dept Chem, Sudbury, ON P3E 2C6, Canada

来源：

MAIN GROUP METAL CHEMISTRY | 1999年 / 22卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new triorganotin(IV) complexes, the trimethyl, tributyl and triphenyl derivatives of 5-(4-chlorophenylazo)salicylic acid, have been synthesised and characterised by H-1, C-13, Sn-119 NMR, IR and elemental analysis and the crystal structure of triphenyltin-5-(4-chlorophenylazo)salicylate is reported. The crystals are monoclinic, space group P2(1)/n with a = 9.566(1) Angstrom, b = 14.550(2) Angstrom, c = 22.528(3) Angstrom, beta = 94.04(1), V = 3127.8(7) Angstrom(3), Z = 4 and D-calc = 1.42 Mg.m(-3). There is an encapsulated molecule of hexane incorporated in the structure. This complex adopts a monomeric distorted tetrahedral configuration with the ligand coordinated via a carboxylate oxygen.

引用

页码：413 / 421

页数：9

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