The synthesis and structural characterization of some triorganothin(IV) complexes of 5-(4-chlorophenylazo)salicylic acid:: Crystal and molecular structure of triphenyltin 5-(4-chlorophenylazo)salicylate•0.5C6H14

被引：0

作者：

Baul, TSB

Dhar, S

Kharbani, N

Pyke, SM

Butcher, R

Smith, FE

机构：

[1] NE Hill Univ, Chem Lab, Reg Sophisticated Instrumentat Ctr, Shillong 793003, Meghalaya, India

[2] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

[3] Howard Univ, Dept Chem, Washington, DC 20059 USA

[4] Laurentian Univ, Dept Chem, Sudbury, ON P3E 2C6, Canada

来源：

MAIN GROUP METAL CHEMISTRY | 1999年 / 22卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new triorganotin(IV) complexes, the trimethyl, tributyl and triphenyl derivatives of 5-(4-chlorophenylazo)salicylic acid, have been synthesised and characterised by H-1, C-13, Sn-119 NMR, IR and elemental analysis and the crystal structure of triphenyltin-5-(4-chlorophenylazo)salicylate is reported. The crystals are monoclinic, space group P2(1)/n with a = 9.566(1) Angstrom, b = 14.550(2) Angstrom, c = 22.528(3) Angstrom, beta = 94.04(1), V = 3127.8(7) Angstrom(3), Z = 4 and D-calc = 1.42 Mg.m(-3). There is an encapsulated molecule of hexane incorporated in the structure. This complex adopts a monomeric distorted tetrahedral configuration with the ligand coordinated via a carboxylate oxygen.

引用

页码：413 / 421

页数：9

共 50 条

[1] Crystal structure of 5-(nitro)-salicylaldehydebenzenesulfonic-4-methylhydrazide, C14H15N3O6S
Feng, Xun
Li, Rong-Fang
Zhang, Yu
Ma, Wen Yan
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2014, 229 (02): : 139 - 140
[2] Crystal　and　Molecular　Structure　of　a　New　Mono－substituted　Titanocene　Complex，｛（η5－Cp）［η5－(1－（4－OCH3）C6H4)C6H10Cp］（TiCl2）｝·0．3(n－C6H14)
Tian Jun
Hu Ning-Hai
Sheng Qi
Huang Bao-Tong (Changchun Institute of Applied Chemistry
结构化学, 1995, (02) : 83 - 87
[3] Synthesis and structural elucidation of some novel aluminium(III) complexes with Schiff bases:: Crystal and molecular structure of [Al{O(C6H4)CH=NC6H5}2{HO(C6H4)CH=NC6H5}2]Br
Jain, AK
Gupta, A
Bohra, R
Lorenz, IP
Mayer, P
POLYHEDRON, 2006, 25 (03) : 654 - 662
[4] Novel heterobimetallic titanium-platinum complexes.: Crystal structure of [(η5-C5H4SiMe3)(SPh)Ti(μ,η5-κS-C5H4P(S)Ph2)(μ-SPh)Pt(C6F5)2]
Delgado, E
Donnadieu, B
Hernández, E
Lalinde, E
Mansilla, N
Moreno, MT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 592 (02) : 283 - 289
[5] The synthesis of olefin, carbonyl and thiolate complexes of platinum(IV) in the [(η5-C5Me5)Pt(IV)] system.: Crystal and molecular structure of (η5-C5Me5)PtMe2[S(p-CH3(C6H4)]
Howard, WA
Bergman, RG
POLYHEDRON, 1998, 17 (5-6) : 803 - 810
[6] Crystal structure of 5-(2,6-dimethyl-4H-pyran-4-ylidene)-1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione, C13H14N2O4
Li, Xiaochuan
Li, Yajuan
Zhang, Junna
Son, Young-A
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2013, 228 (01): : 97 - 98
[7] STRUCTURAL CHEMISTRY OF SOME COBALT CYANIDE AND ISOCYANIDE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF [CO(CNC6H5)5] CLO4.CHCL3
BROWN, LD
GREIG, DR
RAYMOND, KN
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, : 67 - &
[8] SYNTHESIS AND CHARACTERIZATION OF THIOLATE DERIVATIVES OF BIS(TRIMETHYLSILYLCYCLOPENTADIENYL)TITANIUM(IV) - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(ETA(5)-C(5)H(4)SIME(3))(2)TI(SC6F5)(2)]
DELGADO, E
HERNANDEZ, E
HEDAYAT, A
TORNERO, J
TORRES, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 466 (1-2) : 119 - 123
[9] Crystal structure of 3-(2,4-dinitrophenylthio)-5-(2-ethoxyphenyl)-4H-1,2,4-triazol-4-amine, C16H14N6O5S
Ding, Qi-Chun
Huang, Yu-Lin
Jin, Jian-Yu
Zhang, Li-Xue
Fu, Xiao-Dan
Cai, Xiao-Qing
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2009, 224 (01): : 103 - 104
[10] SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF COPPER(I) THIOLATES - [(C6H5)4P+]2[CU4(C2H5S-)6].0.5C2H6O2 AND [(C6H5)4P+][CU7(C2H5S-)8]
BAUMGARTNER, M
SCHMALLE, H
DUBLER, E
POLYHEDRON, 1990, 9 (09) : 1155 - 1164

← 1 2 3 4 5 →