Synthesis of ferrocenylglucose phosphonite and bisphosphinite: Pd(II) and Pt(II) complexes, Pd-catalyzed allylic alkylation

被引：25
|
作者：
Nazarov, AA
Hartinger, CG
Arion, VB
Giester, G
Keppler, BK
机构：
[1] Univ Vienna, Inst Inorgan Chem, A-1090 Vienna, Austria
[2] Univ Vienna, Inst Mineral & Crystallog, A-1090 Vienna, Austria
来源：
TETRAHEDRON | 2002年 / 58卷 / 42期
基金：
奥地利科学基金会;
关键词：
phosphonite; phosphinite; ferrocene; catalysis; enantioselective; coordination compound; palladium; platinum;
D O I：
10.1016/S0040-4020(02)01027-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis and characterization of the new phosphorus containing ligands and the corresponding Pd(Il) and Pt(Il) complexes are reported. The molecular structure of 4,6-bis-O-(diphenylphosphino)-2,3-(ferrocene-1,1'-dicarbonyl)-O-methyl-alpha-D-glucopyranoside was determined by X-ray diffraction methods. The new ligands show good activity (90%) and moderate stereoselectivity (39% ec) in the Pd-catalyzed enantioselective allylic alkylation. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：8489 / 8492
页数：4
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