Synthesis of Glycerol Triacetate Using a Bronsted-Lewis Acidic Ionic Liquid as the Catalyst

被引：7

作者：

Liu, Shiwei ^{[1
]}

Wang, Aiting ^{[1
]}

Liu, Zhiguo ^{[1
]}

Li, Lu ^{[1
]}

Yu, Shitao ^{[1
]}

Xie, Congxia ^{[1
]}

Liu, Fusheng ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 2015年 / 92卷 / 09期

关键词：

Ionic liquid; Esterification; Glycerol triacetate; Catalysis; FATTY-ACIDS; SOLVENT; EFFICIENT; ALCOHOLS; ESTERIFICATION;

D O I：

10.1007/s11746-015-2701-9

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Bronsted-Lewis acidic ionic liquids (IL) were used in the esterification of glycerol and acetic acid to produce glycerol triacetate. The results show that the IL (3-sulfonic acid)-propyltriethylammonium chloroironinate [HO3S-(CH2)(3)-NEt3]Cl-[FeCl3](x) (molar fraction of FeCl3, x = 0.67) was an efficient catalyst for the esterification reaction. The yield of glycerol triacetate and its content were greater than 98 % when reacted under reflux for 4 h. It was observed that a synergistic effect of Bronsted and Lewis acid sites enhanced the catalytic performance of IL. The reusability of IL was good. After six reaction cycles, the glycerol triacetate yield and concentration were still greater than 98 %. Likewise, the Bronsted-Lewis acidic IL was an efficient catalyst for esterification reactions of high boiling points alcohols with acetic acid.

引用

页码：1253 / 1258

页数：6

共 50 条

[41] Facile Synthesis of Acetal Over a Supported Novel Bronsted and Lewis Acid Ionic Liquid Catalyst
Liu, Ruifeng
Dai, Liming
Zhao, Qian
Xie, Yingjie
Jiang, Tingshun
[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (08) : 4396 - 4405
[42] A Bronsted acidic ionic liquid as an efficient and reusable catalyst system for esterification
Zhang, Haibo
Xu, Fei
Zhou, Xiaohai
Zhang, Gaoyong
Wang, Cunxin
[J]. GREEN CHEMISTRY, 2007, 9 (11) : 1208 - 1211
[43] Bronsted Acidic Ionic Liquid as an Efficient Catalyst for Acetylation of Alcohols and Phenols
Hajipour, Abdol R.
Khazdooz, Leila
Ruoho, Arnold E.
[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2009, 56 (02) : 398 - 403
[44] Bronsted acidic ionic liquid as an efficient and reusable catalyst for transesterification of β-ketoesters
Qureshi, Ziyauddin S.
Deshmukh, Krishna M.
Bhor, Malhari D.
Bhanage, Bhalchandra M.
[J]. CATALYSIS COMMUNICATIONS, 2009, 10 (06) : 833 - 837
[45] Efficient synthesis of phytosteryl esters using the Lewis acidic ionic liquid
Yang, Yebo
He, Wensen
Jia, Chengsheng
Ma, Yuan
Zhang, Xiaoming
Feng, Biao
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 357 : 39 - 43
[46] An expeditious synthesis of homoallylic alcohols using Bronsted acidic supported ionic liquid phase catalyst with pendant ferrocenyl group
Rashinkar, Gajanan
Kamble, Santosh
Kumbhar, Arjun
Salunkhe, Rajashri
[J]. CATALYSIS COMMUNICATIONS, 2011, 12 (15) : 1442 - 1447
[47] A Modified and Green Procedure for the Synthesis of β-Amido Ketones Using a Bronsted-Acidic Ionic Liquid as Novel and Reusable Catalyst
Davoodnia, Abolghasem
Heravi, Majid M.
Rezaei-Daghigh, Leila
Tavakoli-Hoseini, Niloofar
[J]. CHINESE JOURNAL OF CHEMISTRY, 2010, 28 (03) : 429 - 433
[48] Optimization of Process Variables in the Synthesis of Tributyl Citrate Using a Polyvinylpolypyrrolidone-Supported Bronsted Acidic Ionic Liquid Catalyst
Wang, Song
Xu, Lanlan
Xu, Linlin
Tian, Chengcheng
Guan, Yinyan
[J]. INTERNATIONAL JOURNAL OF POLYMER SCIENCE, 2018, 2018
[49] Liquid phase catalytic dehydration of glycerol to acrolein over Bronsted acidic ionic liquid catalysts
Shen, Lingqin
Yin, Hengbo
Wang, Aili
Lu, Xiufeng
Zhang, Changhua
Chen, Fen
Wang, Yuting
Chen, Huijuan
[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (03) : 759 - 766
[50] Optimization of Oleic Acid Esterification for Biodiesel Production using Bronsted Acidic Ionic Liquid as a Catalyst
Han, Benyong
Yin, Fang
Liu, Shiqing
Zhao, Xingling
Liu, Jing
Wang, Changmei
Yang, Hong
Zhang, Wudi
[J]. CHIANG MAI JOURNAL OF SCIENCE, 2019, 46 (04): : 714 - 726

← 1 2 3 4 5 →