Synthesis, structural characterization, and photophysics of dinuclear gold(II) complexes [{Au(dppn)Br}2](PF6)2 and [{Au(dppn)I}2](PF6)2 with an unsupported AuII-AuII bond

被引：25

作者：

Yam, VWW ^{[1
]}

Li, CK ^{[1
]}

Chan, CL ^{[1
]}

Cheung, KK ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 27期

关键词：

D O I：

10.1021/ic010744t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of novel dinuclear gold(II) complexes having an unsupported Au(II)-Au(II) bond with well-defined oxidation state at the gold center were synthesized. Red shifts in both the low-energy absorption and emission bands were observed upon increasing the donor ability of the coordinated halogen atoms.

引用

页码：7054 / 7058

页数：5

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