Synthesis, structural characterization, and photophysics of dinuclear gold(II) complexes [{Au(dppn)Br}2](PF6)2 and [{Au(dppn)I}2](PF6)2 with an unsupported AuII-AuII bond

被引：25
|
作者：
Yam, VWW [1 ]
Li, CK [1 ]
Chan, CL [1 ]
Cheung, KK [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 27期
关键词：
D O I：
10.1021/ic010744t
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of novel dinuclear gold(II) complexes having an unsupported Au(II)-Au(II) bond with well-defined oxidation state at the gold center were synthesized. Red shifts in both the low-energy absorption and emission bands were observed upon increasing the donor ability of the coordinated halogen atoms.
引用
收藏
页码：7054 / 7058
页数：5
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