Effects of cations and anions of ionic liquids on the production of 5-hydroxymethylfurfural from fructose

被引：92
|
作者：
Shi, Chunyan [1 ]
Zhao, Yuling [2 ]
Xin, Jiayu [1 ]
Wang, Jinquan [1 ]
Lu, Xingmei [1 ]
Zhang, Xiangping [1 ]
Zhang, Suojiang [1 ]
机构：
[1] Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China
[2] Henan Normal Univ, Key Lab Green Chem Media & React, Minist Educ, Sch Chem & Environm Sci, Xinxiang 453007, Henan, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 34期
基金：
中国国家自然科学基金;
关键词：
CATALYTIC CONVERSION; DEHYDRATION; BIOMASS; SUGARS;
D O I：
10.1039/c2cc30357d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ionic liquids (ILs) with different cations and anions were used to study the effects on 5-hydroxymethylfurfural (HMF) preparation. It was found that both aggregations of cations and hydrogen bonds of anions with fructose played important roles. Molecular dynamics simulations were also performed to explain the experimental results.
引用
收藏
页码：4103 / 4105
页数：3
相关论文
共 50 条
  • [41] Insights into solvent effect on selective production of furfural and 5-hydroxymethylfurfural from fructose
    Li, Rui
    Lin, Qixuan
    Liu, Yao
    Wang, Xiaohui
    Liu, Chuanfu
    Peng, Feng
    Ren, Junli
    JOURNAL OF CATALYSIS, 2023, 424 : 162 - 172
  • [42] The Production of 5-Hydroxymethylfurfural from Fructose in Isopropyl Alcohol: A Green and Efficient System
    Lai, Linke
    Zhang, Yugen
    CHEMSUSCHEM, 2011, 4 (12) : 1745 - 1748
  • [43] Highly Selective and Near-Quantitative Conversion of Fructose to 5-Hydroxymethylfurfural Using Mildly Acidic Ionic Liquids
    Eminov, Sanan
    Wilton-Ely, James D. E. T.
    Hallett, Jason P.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2014, 2 (04): : 978 - 981
  • [44] Production of 5-hydroxymethylfurfural from Glucose Catalyzed by Acidic Ionic Liquid
    Wang, P.
    Ren, L.
    Yu, H.
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2015, 37 (16) : 1729 - 1735
  • [45] Production of 5-Hydroxymethylfurfural from Pine Wood via Biorefinery Technologies Based on Fractionation and Reaction in Ionic Liquids
    Penin, Lucia
    Peleteiro, Susana
    Rivas, Sandra
    Santos, Valentin
    Parajo, Juan Carlos
    BIORESOURCES, 2019, 14 (02) : 4733 - 4747
  • [46] How do isomeric ortho, meta and paradicationic ionic liquids impact the production of 5-hydroxymethylfurfural?
    Yaman, Suhaila M.
    Mohamad, Sharifah
    Manan, Ninie S. A.
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 238 : 574 - 581
  • [47] Molecular Origin for the Difficulty in Separation of 5-Hydroxymethylfurfural from Imidazolium Based Ionic Liquids
    Wang, Huiyong
    Liu, Shuyan
    Zhao, Yuling
    Zhang, Hucheng
    Wang, Jianji
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2016, 4 (12): : 6712 - 6721
  • [48] Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey
    Maric, Aleksandar
    Jovanov, Pavle
    Gadzuric, Slobodan
    Trtic-Petrovic, Tatjana
    Sakac, Marijana
    Tot, Aleksandar
    Bertic, Marko
    Vranes, Milan
    RSC ADVANCES, 2023, 13 (46) : 32714 - 32721
  • [49] Highly efficient separation of 5-hydroxymethylfurfural from imidazolium-based ionic liquids
    Wang, Huiyong
    Cui, Jingjing
    Zhao, Yuling
    Li, Zhiyong
    Wang, Jianji
    GREEN CHEMISTRY, 2021, 23 (01) : 405 - 411
  • [50] Conversion of hexose into 5-hydroxymethylfurfural in imidazolium ionic liquids with and without a catalyst
    Cao, Quan
    Guo, Xingcui
    Yao, Shengxi
    Guan, Jing
    Wang, Xiaoyan
    Mu, Xindong
    Zhang, Dongke
    CARBOHYDRATE RESEARCH, 2011, 346 (07) : 956 - 959
12345