Scaling of volumetric data in model systems based on the Lennard-Jones potential

被引:28
|
作者
Grzybowski, A. [1 ]
Koperwas, K. [1 ]
Paluch, M. [1 ]
机构
[1] Silesian Univ, Inst Phys, PL-40007 Katowice, Poland
来源
PHYSICAL REVIEW E | 2012年 / 86卷 / 03期
关键词
EQUATION-OF-STATE; DYNAMICS; DENSITY; RELAXATION; LIQUIDS; TEMPERATURE; DEPENDENCE; SCATTERING; POLYMERS;
D O I
10.1103/PhysRevE.86.031501
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The crucial problem for better understanding the nature of glass transition and related relaxation phenomena is to find proper interrelations between the molecular dynamics and thermodynamics of viscous systems. To make progress towards this goal the recently observed density scaling of viscous liquid dynamics has been very intensively and successfully studied in the past few years. However, previous attempts at related scaling of volumetric data yielded results inconsistent with those found from the density scaling of molecular dynamics. In this paper, we show that volumetric data obtained from simulations in simple molecular models based on the Lennard-Jones (LJ) potential, such as the Kob-Andersen binary LJ liquid, its repulsive inverse power-law version, and the Lewis-Wahnstrom o-terphenyl model, can be scaled by using the same value of the exponent, which scales dynamic quantities and is directly related to the exponent of the repulsive inverse power law that underlies short-range approximations of the LJ potential.
引用
收藏
页数:9
相关论文
共 50 条
  • [21] Phase Transitions For Dilute Particle Systems with Lennard-Jones Potential
    Andrea Collevecchio
    Wolfgang König
    Peter Mörters
    Nadia Sidorova
    [J]. Communications in Mathematical Physics, 2010, 299 : 603 - 630
  • [22] PHYSICAL REALITY OF LENNARD-JONES POTENTIAL
    NEUGEBAUER, T
    [J]. ACTA PHYSICA ACADEMIAE SCIENTIARUM HUNGARICAE, 1969, 27 (1-4): : 405 - +
  • [23] A "modified Lennard-Jones oscillator" model for diatom potential functions
    Hajigeorgiou, PG
    Le Roy, RJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (09): : 3949 - 3957
  • [24] The potential energy landscape in the Lennard-Jones binary mixture model
    Sampoli, M
    Benassi, P
    Eramo, R
    Angelani, L
    Ruocco, G
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (11) : S1227 - S1236
  • [25] Expansion dynamics of Lennard-Jones systems
    Ison, M. J.
    Gulminelli, F.
    Dorso, C. O.
    [J]. PHYSICAL REVIEW E, 2008, 77 (03):
  • [26] On cellular automata model of traffic flow with Lennard-Jones potential
    Zheng, Weifan
    Cheng, Yang
    Ma, Xiao
    Sui, Hao
    Zhang, Jiye
    [J]. NONDESTRUCTIVE TESTING AND EVALUATION, 2024, 39 (01) : 90 - 101
  • [27] Thermodynamic scaling of diffusion in supercooled Lennard-Jones liquids
    Coslovich, D.
    Roland, C. M.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (05): : 1329 - 1332
  • [28] SCALING BEHAVIOR IN THE DYNAMICS OF A SUPERCOOLED LENNARD-JONES MIXTURE
    KOB, W
    ANDERSEN, HC
    [J]. NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1994, 16 (08): : 1291 - 1295
  • [29] PROPERTIES OF A LINEAR LATTICE OF ATOMS BASED ON LENNARD-JONES POTENTIAL
    GRABEN, HW
    [J]. AMERICAN JOURNAL OF PHYSICS, 1978, 46 (05) : 585 - 585
  • [30] An equation of state for real fluids based on the Lennard-Jones potential
    Sun, TF
    Teja, AS
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (43): : 17365 - 17372