Toward the design of double metal cyanides for the copolymerization of CO2 and epoxides

被引：70

作者：

Darensbourg, DJ ^{[1
]}

Adams, MJ ^{[1
]}

Yarbrough, JC ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 26期

关键词：

D O I：

10.1021/ic0155941

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [KCpFe(CN)(2)PPh2(CH2)(1.5)](2) with zinc iodide results in the formation of a nonplanar diamond-shaped arrangement of [FeCNZn](2) with a bridging diphenyl-phosphinopropane, [CpFe(mu -CN)(2)ZnI(THF)](2)-mu -dppp. This double metal cyanide (DMC) is found to mimic the reactivity of the heterogeneous DMC catalysts. That is, it serves to homogeneously catalyze the coupling of CO2 and cyclohexene oxide to afford cyclic cyclohexene carbonate and low molecular weight polycarbonate.

引用

页码：6543 / +

页数：3

共 50 条

[31] Copolymerization of Epoxides and CO2: Polymer Chemistry for Incorporation in Undergraduate Inorganic Chemistry
Darensbourg, Donald J.
JOURNAL OF CHEMICAL EDUCATION, 2017, 94 (11) : 1691 - 1695
[32] Copolymerization of epoxides and CO2 with homogeneous cobalt-based catalysts.
Cohen, CT
Peretti, KL
Qin, ZQ
Chu, T
Coates, GW
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U796 - U796
[33] Aluminum Porphyrin Foldamer Catalyst Enables Efficient Copolymerization of CO2/Epoxides
Zhou, Zhen-Zhen
Liu, Shun-Jie
Lang, Tao-Tao
Gao, Feng-Xiang
Wang, Xian-Hong
ACTA POLYMERICA SINICA, 2024, 55 (04): : 396 - 406
[34] Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO2 and Epoxides with Unprecedented Efficiency
Yang, Guan-Wen
Zhang, Yao-Yao
Xie, Rui
Wu, Guang-Peng
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (28) : 12245 - 12255
[35] Parallel synthesis of zinc and magnesium alkoxy β-difunctional ligands and their effect on CO2 incorporation in the copolymerization of CO2 with epoxides
Ouattara, Tantiboro S.
Onakoya, Ola O.
Matthews, Jason S.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[36] Two-in-One: Photothermal Ring-Opening Copolymerization of CO2 and Epoxides
Zhuo, Chunwei
Cao, Han
You, Huai
Liu, Shunjie
Wang, Xianhong
Wang, Fosong
ACS MACRO LETTERS, 2022, 11 (07) : 941 - 947
[37] Copolymerization and terpolymerization of CO2 and epoxides using a soluble zinc crotonate catalyst precursor
Darensbourg, DJ
Zimmer, MS
MACROMOLECULES, 1999, 32 (07) : 2137 - 2140
[38] Chiral Organoboron-Mediated Alternating Copolymerization of meso-Epoxides with CO2
Du, Peng
Li, Yao
Lu, Xiao-Bing
MACROMOLECULES, 2023, 56 (17) : 6783 - 6789
[39] Intramolecular synergistic catalysis for asymmetric alternating copolymerization of CO2 and meso-epoxides
Li, Yi-Ning
Yang, Han-Han
Lu, Xiao-Bing
JOURNAL OF POLYMER SCIENCE, 2022, 60 (14) : 2078 - 2085
[40] Nanoparticulate TiO2-Supported Double Metal Cyanide Catalyst for the Copolymerization of CO2 with Propylene Oxide
Subhani, Muhammad Afzal
Guertler, Christoph
Leitner, Walter
Mueller, Thomas Ernst
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (13-14) : 1944 - 1949

← 1 2 3 4 5 →