Solvent-free aerobic epoxidation of 1-decene using supported cobalt catalysts

被引：13

作者：

Engel, Rebecca V. ^{[1
]}

Alsaiari, Raiedhah ^{[1
]}

Nowicka, Ewa ^{[1
,2
]}

Miedziak, Peter J. ^{[1
]}

Kondrat, Simon A. ^{[1
,3
]}

Morgan, David J. ^{[1
]}

Edwards, Jennifer K. ^{[1
]}

Hutchings, Graham J. ^{[1
]}

机构：

[1] Cardiff Univ, Cardiff Catalysis Inst, Sch Chem, Main Bldg,Pk Pl, Cardiff CF10 3AT, S Glam, Wales

[2] Tech Univ Berlin, Inst Chem, Str 17 Juni 124, D-10623 Berlin, Germany

[3] Loughborough Univ, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

CATALYSIS TODAY | 2019年 / 333卷 / 154-160期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

Aerobic epoxidation; Supported cobalt oxide catalysts; Solvent-free epoxidation; METAL-ORGANIC FRAMEWORK; HETEROGENEOUS CATALYSTS; HYDROCARBON OXIDATION; OLEFIN EPOXIDATION; MOLECULAR-OXYGEN; STYRENE; ALKENES; DIMETHYLFORMAMIDE; NANOPARTICLES; REDUCTION;

D O I：

10.1016/j.cattod.2018.09.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this study, active cobalt-based catalysts are reported for the solvent-free aerobic epoxidation of 1-decene as a non-noble metal, alternative to the conventionally used gold catalyst. No sacrificial reductant is applied and air is used as primary oxidant at ambient pressure. The influence of different radical initiators and the product distribution over time is investigated. Evidence for a reaction mechanism similar to the previously reported gold-catalysed aerobic epoxidation of 1-decene, is given. Furthermore, it is shown that the catalyst stability is influenced by the choice of the support.

引用

页码：154 / 160

页数：7

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