Bean-dreg-derived carbon materials used as superior anode material for lithium-ion batteries

被引:68
|
作者
Ru, Haohui [1 ]
Xiang, Kaixiong [1 ]
Zhou, Wei [1 ]
Zhu, Yirong [1 ]
Zhao, Xiu Song [2 ]
Chen, Han [1 ]
机构
[1] Hunan Univ Technol, Coll Met & Mat Engn, Zhuzhou 412007, Peoples R China
[2] Univ Queensland, Sch Chem Engn, Brisbane, Qld 4072, Australia
关键词
Lithium-ion batteries; graphitization; activation; bean dreg; DOPED POROUS CARBON; HIGH-PERFORMANCE; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS; LI STORAGE; BIOMASS; INSERTION; CAPACITY; GRAPHENE; SHELLS;
D O I
10.1016/j.electacta.2016.10.202
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The structures of modified carbons from bean dregs were regulated via graphitization treatment and chemical activation. The microstructure and electrochemical performance were studied using X-ray diffraction, Raman spectrometer, SEM and TEM techniques. The electrochemical performance was investigated using electrochemical methods. After heat-treatment at 2800 degrees C, the obtained BDC-2800 possessed a high degree of graphitization and showed an outstanding cycling performance, delivering capacity decay from 423 to 396 mAh g(-1) at 0.1 C after 100 cycles. The chemical-treated carbons also demonstrated enhanced electrochemical performance, especially for the KOH-treated sample. The BDC-K displayed superior specific charge capacity of 801 mAhg(-1) at 0.1 C, and showed an impressive rate capability of 643 mAhr g(-1) at 1 C. In addition, this sample delivered capacity retention of 94% after 500 cycles at 1 C. This good electrochemical performance was mainly due to its high surface area and abundant mesoporous structure. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:551 / 560
页数:10
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