Cationic tetrapyrrole receptors for selective binding hydroxide ions

被引：0
|
作者：
Kulikova, O. M. [1 ]
Ivanova, Yu. B. [1 ]
Glazunov, A. V. [2 ]
Semeikin, A. S. [2 ]
Mamardashvili, N. Zh. [1 ]
机构：
[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia
[2] Ivanovo State Univ Chem Technol, Ivanovo 153000, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2011年 / 81卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
Porphyrin; General Chemistry; Triflate; Tetrapyrrole; Spectrophotometric Titration;
D O I：
10.1134/S1070363211100252
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The receptor properties of complexes of 5,10,15,20-tetraphenyl-21,22,23-trimethylporphyrin and 5,10,15,20-tetraphenyl-2,3,7,8,12,13,17,18,21,22,23,24-dodecamethylporphyrin toward hydroxide ion were explored by the method of spectrophotometric titration in methanol with iodine and triflate respectively. We found that in the studied complexes the hydroxide ion is replaced by the respective counterion that leads to a strong response in the visible region of absorption spectrum. The formation constants and the concentration ranges of existence of the complexes were determined.
引用
收藏
页码：2193 / 2197
页数：5
相关论文
共 50 条
  • [31] Myoglobin with modified tetrapyrrole chromophores:: Binding specificity and photochemistry
    Proell, Stephanie
    Wilhelm, Brigitte
    Robert, Bruno
    Scheer, Hugo
    BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2006, 1757 (07): : 750 - 763
  • [32] Synthesis and binding study of new aminopyridinyl cavitand receptors for the recognition of cationic guests
    Moon, BS
    Kim, SK
    Kang, BG
    Lee, JH
    Yoon, J
    Lee, KD
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2003, 24 (01) : 133 - 136
  • [33] Analysis of cytosolic tetrapyrrole binding protein in Arabidopsis thaliana
    Takahashi, S
    Masuda, T
    PLANT AND CELL PHYSIOLOGY, 2006, 47 : S130 - S130
  • [34] Synthesis and design of tetrapyrrole molecular receptors for alkali metal cations
    Ivanova, Yu. B.
    Toldina, O. V.
    Sheinin, V. B.
    Marnardashvili, N. Zh.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 43 (09) : 1397 - 1402
  • [35] Selective Uptake of Phosphate Ions on Nanocomposite of ZrO2 and Layered Double Hydroxide
    Chitrakar, Ramesh
    Yamamoto, Takashi
    Wang, Zheng Ming
    Makita, Yoji
    Sonoda, Akinari
    Hirotsu, Takahiro
    ICHEAP-10: 10TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-3, 2011, 24 : 1495 - +
  • [36] INOR 321-Hydroporphyrins as conformationally designed tetrapyrrole receptors
    Senge, Mathias O.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
  • [37] Synthesis and design of tetrapyrrole molecular receptors for alkali metal cations
    Yu. B. Ivanova
    O. V. Toldina
    V. B. Sheinin
    N. Zh. Mamardashvili
    Russian Journal of Organic Chemistry, 2007, 43 : 1397 - 1402
  • [38] SELECTIVE BINDING OF IONS BY POLYELECTROLYTE GELS - VOLUME CHANGE CRITERION
    BOYD, GE
    BUNZL, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (07) : 2054 - 2058
  • [39] SELECTIVE BINDING OF ACTINIDE (IV) IONS BY SIDEROPHORES AND SIDEROPHORE ANALOGS
    WHISENHUNT, DW
    NEU, M
    XU, JD
    HOU, ZG
    HOFFMAN, DC
    RAYMOND, KN
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 163 - IEC
  • [40] Selective binding of rare-earth ions in polymerizable cages
    Ou, Jou-Tsen
    Taylor, Mercedes K.
    CHEMICAL COMMUNICATIONS, 2025, 61 (25)
12345