The shapes of absorption bands due to S0→S1 transitions in photochromic molecules

被引:0
|
作者
Aldoshin, SM [1 ]
Volokhov, VM [1 ]
Poluyanov, LV [1 ]
机构
[1] Russian Acad Sci, Inst Phys Chem, Chernogolovka, Russia
来源
CHEMICAL PHYSICS REPORTS | 1998年 / 17卷 / 10期
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中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The shapes of optical absorption bands of one- and two-proton subsystems of photochromic molecules are calculated by semiclassical methods. The analysis is carried out, assuming that radiation absorption is accompanied by the S-0 --> S-1 electron transition between the nondegenerate singlet states of molecules. A correlation between the band shape and the parameters of the potential is established on a quantitative level.
引用
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页码:1807 / 1815
页数:9
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