Construction of the tetranuclear complex with inter- and intramolecular stacking-like arrangement composed of planar palladium(II) units

被引:0
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作者
Yamada, Y [1 ]
Okamoto, K [1 ]
机构
[1] Univ Tsukuba, Dept Chem, Ibaraki, Osaka 3058571, Japan
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of a square-planar S-donating metalloligand [Pd(aet)(2)] (aet = 2-aminoethanethiolate) with [Pd(NO3)(2)(bpy)] (bpy = 2,2'-bipyridine) gave a new type of S-bridged tetranuclear complex [Pd-4(aet)(4)(bpy)(2)](4+) (1), in which two {Pd(bpy)} moieties are aligned so as to overlap each other by bridging with two [Pd(aet)(2)] units.
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页码:315 / 316
页数:2
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