Polyaniline micro-/nanostructures: morphology control and formation mechanism exploration

被引：29
|
作者：
Li, Yu [1 ]
Zheng, Jian-Long [2 ]
Feng, Jing [1 ]
Jing, Xin-Li [1 ]
机构：
[1] Xi An Jiao Tong Univ, Dept Appl Chem, Sch Sci, 28 Xianning West Rd, Xian 710049, Peoples R China
[2] Construct Engn Res Inst, Gen Logist Dept, Xian 710032, Peoples R China
来源：
CHEMICAL PAPERS | 2013年 / 67卷 / 08期
关键词：
polyaniline; micro-/nanostructure; oligomer; self-assembly; formation mechanism; OXIDATIVE POLYMERIZATION; FACILE SYNTHESIS; NANOSCALE MORPHOLOGY; DIMENSIONAL CONTROL; ASSISTED SYNTHESIS; ANILINE OLIGOMERS; NANOFIBERS; NANOSTRUCTURES; NANOTUBES; TEMPLATE;
D O I：
10.2478/s11696-013-0347-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This article provides a brief overview of recent work by the authors' group as well as related researches reported by others on controlling the morphology and exploring the formation mechanism of typical micro-/nanostructures of polyaniline (PANI) and aniline oligomers through template-free aniline chemical oxidation process. The contents are organised as follows: (i) tuning the morphology of aniline polymerisation products by employing ultrasonic irradiation, mass transfer, and pH profiles; (ii) exploring the formation mechanism of micro-/nanostructures during aniline chemical oxidation through examining the precipitation behaviours of aniline oligomers and polymers in a post-synthetic system; (iii) tailoring PANI micro-/nanostuctures into pre-designed morphology by introducing certain heterogeneous nucleation centres; (iv) application potential of PANI nanofibres in the areas of transparent conductive film, electromagnetic interference-shielding coating and graphene-based electrode materials. This short review concludes with our perspectives on the challenges faced in gaining the exact formation mechanism of PANI micro-/nanostructures and the future research possibility for morphologically precisely controlled PANI micro-/nanostructures.
引用
收藏
页码：876 / 890
页数：15
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