Carbon supported TiN nanoparticles: an efficient bifunctional catalyst for non-aqueous Li-O2 batteries

被引：156
|
作者：
Li, Fujun [1 ,2 ]
Ohnishi, Ryohji [2 ]
Yamada, Yuki [2 ]
Kubota, Jun [2 ]
Domen, Kazunari [2 ]
Yamada, Atsuo [2 ]
Zhou, Haoshen [1 ,2 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Inst Energy Technol, Tsukuba, Ibaraki 3058568, Japan
[2] Univ Tokyo, Dept Engn, Bunkyo Ku, Bldg 5-607,7-3-1 Hongo, Tokyo 1138656, Japan
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 12期
关键词：
HIGH-PERFORMANCE; AIR BATTERY; LITHIUM; ARRAYS; O-2;
D O I：
10.1039/c2cc37042e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Li-O-2 battery with TiN nanoparticles supported on Vulcan XC-72, n-TiN/VC, as the cathode catalyst presented an onset potential for the oxygen evolution reaction (OER) at 2.9 V, contrasting with a mixture of micro-sized TiN and VC (m-TiN/VC), and VC, both at similar to 3.1 V. The discharge-recharge voltage gap of n-TiN/VC was estimated to be 1.05 V, which is 390 and 450 mV smaller than that of m-TiN/VC and VC, respectively, at 50 mA g(carbon)(-1). These indicate that n-TiN/VC can function as both an active ORR catalyst during discharge and an efficient OER catalyst during recharge.
引用
收藏
页码：1175 / 1177
页数：3
相关论文
共 50 条
  • [31] An Efficient Multifunctional Soluble Catalyst for Li-O2 Batteries
    Xing, Shuochao
    Zhang, Zhengcai
    Dou, Yaying
    Li, Minghui
    Wu, Jing
    Zhang, Zhang
    Zhou, Zhen
    CCS CHEMISTRY, 2024, 6 (07): : 1810 - 1820
  • [32] Enhancing Effect of Carbon Surface in the Non-Aqueous Li-O2 Battery Cathode
    Nakanishi, Shinji
    Mizuno, Fuminori
    Abe, Takeshi
    Iba, Hideki
    ELECTROCHEMISTRY, 2012, 80 (10) : 783 - 786
  • [33] Multiporous MnCo2O4 Microspheres as an Efficient Bifunctional Catalyst for Nonaqueous Li-O2 Batteries
    Ma, Shunchao
    Sun, Liqun
    Cong, Lina
    Gao, Xuguang
    Yao, Cen
    Guo, Xin
    Tai, Linghua
    Mei, Peng
    Zeng, Yanping
    Xie, Haiming
    Wang, Rongshun
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (49): : 25890 - 25897
  • [34] Low-Cost Nickel Phosphide as an Efficient Bifunctional Cathode Catalyst for Li-O2 Batteries
    Hou, Xiaoyan
    Jiang, Yufeng
    He, Yu-Shi
    Ma, Zi-Feng
    Yang, Jun
    Yuan, Xianxia
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (11) : A2904 - A2908
  • [35] A new electrolyte with good compatibility to a lithium anode for non-aqueous Li-O2 batteries
    Shi, Yanqiong
    Miao, Rongrong
    Li, Lei
    Yang, Jun
    Wang, Jiulin
    Nuli, Yanna
    RSC ADVANCES, 2016, 6 (53): : 47820 - 47823
  • [36] A Modeling Study of the Cycling Behavior of Non-Aqueous Li-O2/CO2 Batteries
    Wang, Yuanhui
    Hao, Liang
    Bai, Minlin
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 168 (02)
  • [37] Mesoporous CuCo2O4 nanoparticles as an efficient cathode catalyst for Li-O2 batteries
    Wang, Peng-Xiang
    Shao, Lin
    Zhang, Nai-Qing
    Sun, Ke-Ning
    JOURNAL OF POWER SOURCES, 2016, 325 : 506 - 512
  • [38] High-efficient CoPt/activated functional carbon catalyst for Li-O2 batteries
    Xia, Han
    Xie, Qifan
    Tian, Yuhui
    Chen, Qiang
    Wen, Ming
    Zhang, Jianli
    Wang, Yao
    Tang, Yiping
    Zhang, Shanqing
    NANO ENERGY, 2021, 84
  • [39] Oxide-on-metal as an inverted design of oxygen electrocatalysts for non-aqueous Li-O2 batteries
    Qu, Jianglan
    Lu, Meihua
    Xu, Chaohe
    Ding, Bo
    Zhan, Yi
    Yang, Jun
    Lee, Jim Yang
    NANOSCALE, 2014, 6 (21) : 12324 - 12327
  • [40] Oxygen reactions in the non-aqueous rechargeable Li-O2 battery
    Peng, Zhangquan
    Freunberger, Stefan A.
    Chen, Yuhui
    Bruce, Peter G.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
12345