Fluorescence line narrowing and decay dynamics in sol-gel glasses containing Eu3+

被引:14
|
作者
Silversmith, AJ [1 ]
Boye, DM
Anderman, RE
Brewer, KS
机构
[1] Hamilton Coll, Dept Phys, Clinton, NY 13323 USA
[2] Davidson Coll, Davidson, NC 28036 USA
关键词
europium; sol-gel glass; fluorescence line narrowing;
D O I
10.1016/S0022-2313(01)00298-8
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Fluorescence line narrowing and emission decay measurements on Eu3+ doped sol-gel glasses have been used to investigate and compare local Eu3+ environments in binary SiO2-TiO2 glasses, SiO2 glasses containing Al3+, and SiO2 glasses without co-dopant. In particular, clustering of rare-earth ions and the effects of annealing temperature on residual hydroxide concentration are studied. The Al and Ti co-doped samples show pronounced line-narrowing implying little energy migration among Eu3+ ions. The D-5(0)-F-7(J) fluorescence decays are faster in the Ti glasses. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:275 / 278
页数:4
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