Study of chirality and photo-induced chirality in cobaloxime complex crystals

被引：4

作者：

Ikeda, K

Liu, WT

Shen, YR

Uekusa, H

Ohashi, Y

Koshihara, S

机构：

[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

[2] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

[3] ERATO, JST, Meguro Ku, Tokyo 1528551, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 422卷 / 1-3期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.cplett.2006.02.090

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We measured circular dichroism (CD) of hydrated and non-hydrated powder crystals of cobaloxime complex. The CD spectrum was found to depend on the crystalline forms. Non-hydrated crystals exhibited an extra pair of exciton-split CD peaks associated with the chiral molecular arrangement in the crystals. We also made direct observation of a photo-induced chirality change or switching in the alkyl ligand of the cobaloxime complex in both crystalline forms. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：267 / 270

页数：4

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