N-Heterocyclic Carbene Catalyzed Sulfenylation of α,β-Unsaturated Aldehydes

被引：38
|
作者：
Dong, Yu-Ting [1 ]
Jim, Quan [1 ]
Zhou, Ling [1 ]
Chen, Jie [1 ]
机构：
[1] Northwest Univ, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Dept Chem & Mat Sci, Xian 710127, Peoples R China
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 21期
基金：
中国国家自然科学基金;
关键词：
BAYLIS-HILLMAN REACTION; SULFUR BOND FORMATION; CARBON-SULFUR; BRESLOW INTERMEDIATE; NHC CATALYSIS; UMPOLUNG; ACTIVATION; ACYL; THIOESTERIFICATION; ORGANOCATALYSIS;
D O I：
10.1021/acs.orglett.6b02939
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient N-heterocyclic carbene (NHC) catalyzed sulfenylation reaction of alpha,beta-unsaturated aldehydes with N-(arylthio)phthalimide has been developed. A wide variety of alpha-thioenals can be obtained with good to excellent yields and excellent Z-configuration.
引用
收藏
页码：5708 / 5711
页数：4
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