Deposition of transparent conductive indium oxide by atmospheric-pressure plasma jet

Indium (III) beta-diketonate complexes were employed as the solid precursor sources in the atmospheric-pressure plasma chemical vapor deposition of indium oxide films using He carrier gas, O-2 reactant gas and growth temperatures from 25 to 250 degrees C. Ellipsometry and X-ray reflectivity showed that the films varied in thicknesses from 40 to 70 nm over the 30 cm(2) deposition growth area for a 12 min duty cycle. The as-deposited films exhibit transmittance in excess of 90% over the visible spectrum while maintaining resistivity on the order of 10(-2) Omega cm. Improved electrical properties (i.e., rho<10(-3) Omega cm) were observed after thermal treatment (T similar to 200 degrees C) in a controlled gas ambient tube furnace. (C) 2008 Elsevier B.V. All rights reserved.