Metallophthalocyanines catalyzed cyclopropanation of olefins with trimethylsilyldiazomethane: A facile and stereoselective synthesis of silylcyclopropanes

被引：21
|
作者：
Sharma, Vishal B. [1 ]
Jain, Suman L. [1 ]
Sain, Bir [1 ]
机构：
[1] Indian Inst Petr, Chem & Biotechnol Div, Dehra Dun 248005, Uttar Pradesh, India
来源：
CATALYSIS COMMUNICATIONS | 2006年 / 7卷 / 07期
关键词：
silylcyclopropanes; metallophthalocyanines; trimethylsilyldiazomethane; cyclopropanation; olefin;
D O I：
10.1016/j.catcom.2005.12.027
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metallophthalocyanines were found to be potent and versatile catalysts for the stereoselective synthesis of C-silyl cyclopropanes with high trans-selectivity by the reaction of olefins with trimethylsilyldiazomethane. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：454 / 456
页数：3
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