Transport through random arrays of conductive cylinders dispersed in a conductive matrix

被引:19
|
作者
Tomadakis, MM
Sotirchos, SV
机构
[1] FLORIDA INST TECHNOL,DIV ENGN SCI,CHEM ENGN PROGRAM,MELBOURNE,FL 32901
[2] UNIV ROCHESTER,DEPT CHEM ENGN,ROCHESTER,NY 14627
来源
JOURNAL OF CHEMICAL PHYSICS | 1996年 / 104卷 / 17期
关键词
D O I
10.1063/1.471356
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present computer simulation results for the effective conductivities of random dispersions of cylinders of arbitrary conductivity relative to that of the matrix phase. The cylinders are randomly positioned in space with their axes parallel to a line, parallel to a plane, or without preferred orientation. Effective conductivities are computed from the mean square displacement of carriers traveling in the two-phase medium according to a discrete step-by-step random walk mechanism. The probability that a carrier colliding with the interface will be reflected back into its phase of travel or cross into the other phase is determined on the basis of the conductivities of the two phases meeting at the interface. The computed values of effective conductivity are compared with variational bounds and analytical approximations of the literature. (C) 1996 American Institute of Physics.
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页码:6893 / 6900
页数:8
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