Preparation and characterization of silicon monoxide/graphite/carbon nanotubes composite as anode for lithium-ion batteries

被引:58
|
作者
Ren, Yurong [1 ]
Ding, Jianning [1 ]
Yuan, Ningyi [1 ]
Jia, Shuyong [2 ]
Qu, Meizhen [3 ]
Yu, Zuolong [3 ]
机构
[1] Changzhou Univ, Ctr Low Dimens Mat Micronano Devices & Syst, Changzhou 213164, Peoples R China
[2] Changzhou Inst Chem, Changzhou 213164, Peoples R China
[3] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
关键词
Silicon monoxide; Graphite; In situ grown; Chemical vapor deposition; Anode; Li-ion battery; WALL CARBON NANOTUBES; ELECTROCHEMICAL INTERCALATION; GRAPHITE; CAPACITY; PERFORMANCE; STORAGE; ROPES;
D O I
10.1007/s10008-011-1525-2
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Silicon monoxide/graphite/multi-walled carbon nanotubes (SiO/G/CNTs) material was prepared by ball milling followed by chemical vapor deposition method and characterized by X-ray diffraction, scanning electron microscopy (SEM), galvanostatic charge-discharge, and AC impedance spectroscopy, respectively. The results revealed that SiO/G/CNTs exhibited an initial specific discharge capacity of 790 mAh g(-1) with a columbic efficiency of 65%. After 100 cycles, a high reversible capacity of 495 mAh g(-1) is still retained. The improved electrochemical properties were due to beneficial SEI by the SEM and EIS results.
引用
收藏
页码:1453 / 1460
页数:8
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