A multinuclear magnetic resonance study of transformations of ruthenium(II) nitrosyl chloride complexes in aqueous solutions

被引：17
|
作者：
Emel'yanov, V. A. [1 ,2 ]
Fedotov, M. A. [3 ]
Belyaev, A. V. [1 ]
Tkachev, S. V. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 58卷 / 08期
关键词：
BEDT-TTF; HYDROLYSIS; CRYSTAL; KINETICS; LIGANDS; SALTS; TOOL; NO; RU;
D O I：
10.1134/S003602361308007X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Aqueous solutions of ruthenium nitrosyl chloride complexes have been studied by(14)N, N-15, O-17, Ru-99, and Cl-35 NMR. Individual complex species have been identified and the corresponding chemical shifts have been determined. The primary aquation product of the pentachloronitrosylruthenate ion is the cis-[RuNO(H2O)Cl-4](-) complex, which subsequently undergoes isomerization. The equilibrium constants of interconversions of ruthenium nitrosyl chloride complexes in an aqueous solution at room temperature have been estimated.
引用
收藏
页码：956 / 963
页数：8
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