Synthesis and properties of trimethylolpropane trioleate as lubricating base oil

被引：27
|
作者：
Wu, Yanxia [1 ,2 ]
Li, Weimin [2 ]
Wang, Xiaobo [2 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
来源：
LUBRICATION SCIENCE | 2015年 / 27卷 / 06期
关键词：
trimethylolpropane trioleate; polyol ester; lubricant; performance evaluation; EPOXIDIZED SOYBEAN OIL; LOW-TEMPERATURE PROPERTIES; OLEIC-ACID; OXIDATIVE STABILITY; POLYOL ESTERS; ESTERIFICATION; STOCKS; ADDITIVES;
D O I：
10.1002/ls.1287
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Trimethylolpropane trioleate (TMPTO) has been prepared by esterification of oleic acid with trimethylolpropane (TMP) without solvent in the presence of solid acid catalyst. The synthesised TMPTO was characterised by infrared spectroscopy, and its physicochemical properties were also evaluated. The compatibilities of TMPTO as lubricant base stock with several conventional additives for mineral oils were investigated. The results showed that the synthesised TMPTO exhibited excellent viscosity-temperature property and low temperature fluidity, high flash point, good foaming stability, hydrolytic stability, and lubricity. In addition, TMPTO possessed good compatibility with conventional additives designed for mineral oils. In particular, zinc dialkyl dithiophosphates as extreme pressure and anti-wear additive exhibited good extreme pressure and anti-wear properties in TMPTO. Therefore, the synthesised TMPTO can be used as potential lubricating base oil due to its excellent comprehensive performance. Copyright (c) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码：369 / 379
页数：11
相关论文
共 50 条
  • [41] BASE MATERIALS OF LUBRICATING OILS - MINERAL-OIL
    FUJITA, M
    JOURNAL OF JAPAN SOCIETY OF LUBRICATION ENGINEERS, 1973, 18 (12): : 925 - 930
  • [42] Thermal Degradation of Aviation Synthetic Lubricating Base Oil
    Nan Wu
    Zhimin Zong
    Yiwei Fei
    Jun Ma
    Feng Guo
    Petroleum Chemistry, 2018, 58 : 250 - 257
  • [43] Effects of VI improver on the lubricating performances of base oil
    Song, Shiyuan
    Fan, Xinhua
    Run Hua Yu Mi Feng/Lubrication Engineering, (02): : 17 - 20
  • [44] Conversion of waste plastic to lubricating base oil.
    Miller, SJ
    Shah, N
    Huffman, GP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U604 - U604
  • [45] Thermal Degradation of Aviation Synthetic Lubricating Base Oil
    Wu, Nan
    Zong, Zhimin
    Fei, Yiwei
    Ma, Jun
    Guo, Feng
    PETROLEUM CHEMISTRY, 2018, 58 (03) : 250 - 257
  • [46] Lubricating properties of water in oil emulsions
    Benner, JJ
    Sadeghi, F
    Hoeprich, MR
    Frank, MC
    JOURNAL OF TRIBOLOGY-TRANSACTIONS OF THE ASME, 2006, 128 (02): : 296 - 311
  • [47] THE LUBRICATING PROPERTIES OF USED ENGINE OIL
    KAWAMURA, M
    FUJITA, K
    NINOMIYA, K
    WEAR, 1982, 77 (02) : 195 - 202
  • [48] PROPERTIES OF LUBRICATING OIL PREPARED BY THERMODIFFUSION
    CHRISTAK.D
    ECKARDT, H
    ERDOL UND KOHLE ERDGAS PETROCHEMIE, 1969, 22 (04): : 226 - &
  • [49] Synthesis and Characterization of Palm Kernel Oil Based Trimethylolpropane Ester
    Salih, Nadia
    Salimon, Jumat
    Jantan, Farah Nadiah
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (17) : 9751 - 9754
  • [50] Activity of Calcium Methoxide Catalyst for Synthesis of High Oleic Palm Oil Based Trimethylolpropane Triesters as Lubricant Base Stock
    Chang, Teck-Sin
    Masood, Hassan
    Yunus, Robiah
    Rashid, Umer
    Choong, Thomas S. Y.
    Biak, Dayang Radiah Awang
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (15) : 5438 - 5442
12345