Photoelectron spectrum of a polycyclic aromatic nitrogen heterocyclic anion: quinoline-

被引：5
|
作者：
Buytendyk, Allyson M. [1 ]
Wang, Yi [1 ]
Graham, Jacob D. [1 ]
Kandalam, Anil K. [2 ]
Kiran, Boggavarapu [3 ]
Bowen, Kit H. [1 ]
机构：
[1] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA
[2] West Chester Univ Penn, Dept Phys, W Chester, PA USA
[3] McNeese State Univ, Dept Chem, Lake Charles, LA 70605 USA
来源：
MOLECULAR PHYSICS | 2015年 / 113卷 / 15-16期
基金：
美国国家科学基金会;
关键词：
density functional theory; electron affinity; molecular anion; photoelectron spectroscopy; gas phase; IONIZATION-POTENTIALS; ELECTRON-AFFINITIES; DIPOLE MOMENTS; ISOQUINOLINE; DERIVATIVES; RESONANCES; MOLECULES;
D O I：
10.1080/00268976.2014.1003261
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report a joint photoelectron spectroscopic and theoretical study on the molecular anion, quinoline(-). Analysis of the vibrationally resolved photoelectron spectrum found the adiabatic electron affinity, EA(a)(C9H7N), to be 0.16 +/- 0.05eV. These findings were supported by density functional theory calculations. Our experimental and computational results demonstrate the unusual electrophilicity for a polycyclic aromatic heterocycle.
引用
收藏
页码：2095 / 2098
页数：4
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