pH-Dependent Assembly of Two Zinc(II) Complexes With 3,4,7,8-Tetramethyl-1,10-Phenanthroline and 4,4-Oxydiphthalic Acid: Synthesis, Characterization, and Crystal Structures

被引：1
|
作者：
Wang, Jun [1 ]
Tao, Jian-Qing [1 ]
Xu, Xiao-Juan [1 ]
Tan, Chun-Yun [1 ]
机构：
[1] Yancheng Teachers Coll, Dept Chem, Yancheng 224002, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 04期
关键词：
3; 4; 7; 8-tetramethyl-1; 10-phenanthroline; 4-oxydiph thalic acid; crystal structure; pH value; LIGAND;
D O I：
10.1080/15533174.2012.740728
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two zinc(II) complexes, namely [Zn(tmphen)2(H2odpa)]center dot 0.88H2O (1) and [Zn(tmphen)2(H2odpa)]n (2) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline, H4odpa = 4,4-oxydiphthalic acid), have been successfully synthesized at different pH values under hydrothermal conditions. In complex 1, the mononuclear [Zn(tmphen)2(H2odpa)]center dot 0.88H2O units are bridged by hydrogen bonds and CH center dot center dot center dot interactions. In 2, H2odpa2 ligands act as bridges between neighboring Zn atoms to form a one-dimensional chain. The structural diversities of 1 and 2 reveal that the pH value of the reaction system plays a crucial role in the assembly of coordination polymer solids.
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页码：456 / 460
页数：5
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