Metal-Catalyzed C(sp2)-N Bond Formation

被引：14
|
作者：
Correa, Arkaitz [1 ]
Bolm, Carsten [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
AMINATION AND FORMATION OF SP2 C-N BONDS | 2013年 / 46卷
关键词：
Copper; Cross-coupling; Enamide; Enamine; Metal catalysis; Palladium; Vinylation; AEROBIC OXIDATIVE AMINATION; CROSS-COUPLING REACTIONS; POTASSIUM ALKENYLTRIFLUOROBORATE SALTS; NITROGEN-CONTAINING HETEROCYCLES; INTRAMOLECULAR N-VINYLATION; HIGHLY EFFICIENT SYNTHESIS; ULLMANN-TYPE REACTION; C-H BONDS; ARYL HALIDES; STEREOSELECTIVE-SYNTHESIS;
D O I：
10.1007/3418_2012_57
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
During the last decades a powerful set of protocols featuring C(sp(2))-N bond formation have emerged as convenient alternatives for the assembly of enamine and enamides. Those methods consist of mostly palladium-catalyzed oxidative amidations of alkenes and both palladium- and copper-catalyzed cross-couplings between generally vinyl halides or pseudohalides and amines or amides. In this review recent advances in both types of processes will be disclosed. Additionally, the synthetic value of the title processes will be illustrated by describing relevant total syntheses of natural products involving vinylation process as the key step.
引用
收藏
页码：55 / 85
页数：31
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