Preparative synthesis of Poly[(R)-3-hydroxybutyrate] monomer for enzymatic cell-free polymerization

被引：10
|
作者：
Tomizawa, Satoshi [1 ]
Yoshioka, Masako [1 ]
Ushimaru, Kazunori [1 ]
Tsuge, Takeharu [1 ]
机构：
[1] Tokyo Inst Technol, Dept Innovat & Engn Mat, Midori Ku, Yokohama, Kanagawa 2268502, Japan
来源：
POLYMER JOURNAL | 2012年 / 44卷 / 09期
关键词：
beta-butyrolactone; coenzyme A; crotonic anhydride; ester exchange reaction; PHA synthase; (R)-specific enoyl-CoA hydratase; IN-VITRO SYNTHESIS; POLY(3-HYDROXYBUTYRIC ACID); THERMAL-DEGRADATION; RALSTONIA-EUTROPHA; POLYHYDROXYALKANOATE; SYNTHASE; MECHANISM; SYSTEM;
D O I：
10.1038/pj.2012.34
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this study, we developed a method to prepare (R)-3-hydroxybutyryl-CoA for enzymatic cell-free polymerization, using crotonic anhydride as a starting material.[graphic not available: see fulltext]
引用
收藏
页码：982 / 985
页数：4
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