Redox-Selective Generation of Aldehydes and H2 from Alcohols under Visible Light

被引：34
|
作者：
Liu, Zijun [1 ]
Caner, Joaquim [1 ]
Kudo, Akihiko [2 ]
Naka, Hiroshi [1 ]
Saito, Susumu [3 ,4 ]
机构：
[1] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Tokyo Univ Sci, Fac Sci, Dept Appl Chem, Shinjyuku Ku, Tokyo 1628601, Japan
[3] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[4] Nagoya Univ, Inst Adv Res, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 29期
关键词：
alcohols; aldehydes; dehydrogenation; heterogeneous photosynthesis; visible light; DEHYDROGENATIVE OXIDATION; PHOTOCATALYTIC DEHYDROGENATION; DOPED SRTIO3; WATER; CONVERSION; DRIVEN; NANOPARTICLES; ACCEPTORLESS; DIHYDROGEN; COMPLEXES;
D O I：
10.1002/chem.201301347
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photosynthetic dehydrogenation: Potential usefulness of visible-light-induced dehydrogenation of alcohols in organic synthesis was demonstrated, in which aldehydes and H2 were afforded by using Ru/SrTiO3:Rh and water (see scheme). Water was essential for the reaction. High efficiency (TON: up to 15 400 based on Rh; H2 and aldehyde evenly generated) and high selectivity were achieved. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9452 / 9456
页数：5
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