Femtosecond nuclear motion of HCl probed by resonant x-ray Raman scattering in the Cl 1s region

被引：63
|
作者：
Simon, M
Journel, L
Guillemin, R
Stolte, WC
Minkov, I
Gel'mukhanov, F
Salek, P
Ågren, H
Carniato, S
Taïeb, R
Hudson, AC
Lindle, DW
机构：
[1] Lab Chim Phys Mat & Rayonnement, UMR 7614, F-75231 Paris 05, France
[2] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA
[3] Royal Inst Technol, S-10691 Stockholm, Sweden
来源：
PHYSICAL REVIEW A | 2006年 / 73卷 / 02期
关键词：
D O I：
10.1103/PhysRevA.73.020706
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Femtosecond dynamics are observed by resonant x-ray Raman scattering (RXS) after excitation along the dissociative Cl 1s -> 6 sigma(*) resonance of gas-phase HCl. The short core-hole lifetime results in a complete breakdown of the common nondispersive behavior of soft-x-ray transitions between parallel potentials. We evidence a general phenomenon of RXS in the hard-x-ray region: a complete quenching of vibrational broadening. This opens up a unique opportunity for superhigh resolution x-ray spectroscopy beyond vibrational and lifetime limitations.
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页数：4
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