STRUCTURE AND CHARACTERIZATION OF A NEW INORGANIC-ORGANIC HYBRID COMPLEX OF Zn(II) WITH 2-AMINO-4-METHYLPYRIDINE

被引：0

作者：

Ben, I. ^{[1
]}

Kefi, Gharbia R. ^{[1
]}

Ben Nasr, C. ^{[1
]}

Durif, A. ^{[2
]}

机构：

[1] Fac Sci Bizerte, Lab Chim Mat, Zarzouna 7021, Tunisia

[2] LEDSS, F-39041 Grenoble 09, France

来源：

REVUE ROUMAINE DE CHIMIE | 2008年 / 53卷 / 03期

关键词：

2-amino-4-methylpyridine; organic-inorganic hybrid; pi-pi interactions; Nuclear Magnetic Resonance (NMR);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new inorganic-organic hybrid complex of Zn(II) with 2-amino-4-methylpyridine, (C6H9N2)(2)ZnCl4, has been prepared and characterized by X-ray crystallography,thermal analysis and solid state NMR spectroscopy. The complex crystallizes in the triclinic space group P (l) over bar with a minimal tetrahedral distortion of the ZnCl42- ion, a = 7.473(2)angstrom, b = 8.469(3) angstrom, c = 15.376(8) angstrom, alpha = 95.14(2)degrees, beta = 91.15(2)degrees, gamma = 68.99(2)degrees, V = 904.79(2)angstrom(3), Z = 2, In this complex, hydrogen bonding and pi-pi interaction play Crucial roles in forming interesting structural patterns. The two pyridinium cations are aligned with each other in a face-to-face manner of electron receiving to donating center. Solid state C-13 CP-MAS-NMR spectroscopy is in agreement with the X-ray structure.

引用

页码：169 / 175

页数：7

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