Features of the Formation of Thin Films of Supersaturated Cd x Pb1-x S Solid Solutions by Chemical Bath Deposition

被引：6
|
作者：
Maskaeva, L. N. [1 ,2 ]
Kutyavina, A. D. [1 ]
Markov, V. F. [1 ,2 ]
Vaganova, I. V. [1 ]
Voronin, V. I. [3 ]
机构：
[1] Yeltsin Ural Fed Univ, Ul Mira 19, Ekaterinburg 620002, Russia
[2] Ural Inst State Fire Serv Emercom Russia, Ekaterinburg, Russia
[3] Russian Acad Sci, Mikheev Inst Met Phys, Ural Branch, Ekaterinburg, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 02期
关键词：
hydrochemical deposition; lead sulfide; cadmium sulfide; supersaturated substitutional solid solutions; AQUEOUS-SOLUTIONS; SOLAR-CELLS; CDXPB1-XS; CRYSTALLIZATION; NUCLEATION; NANOWIRES; MECHANISM;
D O I：
10.1134/S1070363218020172
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Thin nanostructured films of lead sulfide-based CdxPb1-xS solid solutions, strongly supersaturated with respect to the substituting component, were prepared by hydrochemical deposition from ammonia-citrate, ethylenediamine-citrate, and ethylenediamine reaction mixtures onto glass-ceramic substrates. The structure, composition, and morphology of the resulting films were examined. An interesting feature of the synthesis was revealed, a distinct correlation between the linear dimensions of the crystallites constituting the films and the cadmium sulfide content therein: the higher cadmium sulfide content, the smaller were the crystallites.
引用
收藏
页码：295 / 304
页数：10
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