Studies on Thermodynamic Properties of FOX-7 and Its Five Closed-Loop Derivatives

被引：35
|
作者：
Sun, Qian [1 ,2 ]
Zhang, Yu [1 ,2 ]
Xu, Kangzhen [1 ,2 ]
Ren, Zhaoyu
Song, Jirong [1 ,2 ]
Zhao, Fengqi [3 ]
机构：
[1] Northwest Univ, Coll Chem Engn, Xian 710069, Peoples R China
[2] Northwest Univ, Inst Photon & Photon Technol, Xian 710069, Peoples R China
[3] Xian Modern Chem Res Inst, Xian 710065, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2015年 / 60卷 / 07期
基金：
中国国家自然科学基金;
关键词：
THERMAL-BEHAVIOR; 1,1-DIAMINO-2,2-DINITROETHYLENE FOX-7; STRUCTURAL-CHARACTERIZATION; THERMOCHEMICAL PROPERTIES; THEORETICAL CALCULATION; ENERGETIC MATERIAL; HEAT-CAPACITY; CRYSTAL; DECOMPOSITION; MECHANISM;
D O I：
10.1021/acs.jced.5b00021
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Combustion heats of FOX-7 and its five closed-loop derivatives were determined and the standard molar enthalpies of formation (Delta H-f(m)o) were obtained. The sequence of combustion heat for the six compounds is DNDH > MDNZ > DNDX > DNDZ > DDNI > FOX-7. Combustion heat tends to rise with the increase of the number of C atoms in the molecule. Specific heat capacities were measured, and the standard molar heat capacities of the six compounds are (176.59, 205.41, 207.76, 218.89, 217.76, and 215.40) J.mol(-1).K-1, respectively. The specific heat capacity presents an opposite change rule with combustion heat. To the isomers and the introduction of hydroxyl group, the change rule is the same. Moreover, the introduction of hydroxyl group can markedly decrease the combustion heat and specific heat capacity.
引用
收藏
页码：2057 / 2061
页数：5
相关论文
共 50 条
  • [41] Controllable Preparation and Thermochemical Properties of Ultrafine FOX-7 by Microfluidic Crystallization Strategy
    Jiang, Hanyu
    Wang, Xuanjun
    Xu, Siyu
    Yu, Jin
    Zhang, Zihao
    Mu, Xiaogang
    Huang, Taizhong
    Zhao, Fengqi
    ACS OMEGA, 2025,
  • [42] Accuracy of CGM During Closed-Loop Home Studies
    Kowalski, Aaron J.
    Crabtree, Vincent P.
    DIABETES TECHNOLOGY & THERAPEUTICS, 2015, 17 (11) : 770 - 772
  • [43] Preparation and Properties of PBXs Based on FOX-7 in Controlled Fragmentation Warhead Application
    Karim K Elsharkawy
    Lin Guo
    Ahmed M Enew
    含能材料, 2018, 26 (10) : 843 - 849
  • [44] BATCH STUDIES ON A CLOSED-LOOP AIR STRIPPING PROCESS
    BHOWMICK, M
    SEMMENS, MJ
    WATER RESEARCH, 1994, 28 (09) : 2011 - 2019
  • [45] Closed-loop color control spreads its wings
    Mortimer, Pamela
    HVP High Volume Printing, 2001, 19 (06): : 14 - 19
  • [46] CLOSED-LOOP AUTOCORRELATOR AND ITS APPLICATION TO FREQUENCY DISCRIMINATION
    MESSER, H
    BARNESS, Y
    IEE PROCEEDINGS-F RADAR AND SIGNAL PROCESSING, 1986, 133 (01) : 25 - 33
  • [47] Closed-loop transmit diversity schemes for five and six transmit antennas
    Milleth, JK
    Giridhar, K
    Jalihal, D
    IEEE SIGNAL PROCESSING LETTERS, 2005, 12 (02) : 130 - 133
  • [48] Optimal controller properties from closed-loop experiments
    Kammer, LC
    Bitmead, RR
    Bartlett, PL
    AUTOMATICA, 1998, 34 (01) : 83 - 91
  • [49] Closed-Loop Identification of Baroreflex Properties in the Frequency Domain
    Kawada, Toru
    Saku, Keita
    Miyamoto, Tadayoshi
    FRONTIERS IN NEUROSCIENCE, 2021, 15
  • [50] Closed-loop control of product properties in metal forming
    Allwood, J. M.
    Duncan, S. R.
    Cao, J.
    Groche, P.
    Hirt, G.
    Kinsey, B.
    Kuboki, T.
    Liewald, M.
    Sterzing, A.
    Tekkaya, A. E.
    CIRP ANNALS-MANUFACTURING TECHNOLOGY, 2016, 65 (02) : 573 - 596
12345