Synthesis, characterization and emission study of zinc(II) and cobalt(II) complexes: Bis(bidentate) iminophenols as zinc(II) selective fluorescence probes

被引：15
|
作者：
Chakraborty, Biswarup [1 ]
Halder, Partha [1 ]
Chakraborty, Sourav [1 ]
Das, Oindrila [1 ]
Paria, Sayantan [1 ]
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, India
来源：
INORGANICA CHIMICA ACTA | 2012年 / 387卷
关键词：
Iminophenol; Zinc; Fluorescence; Cobalt; Solid state structures; BINDING-PROTEIN; SCHIFF-BASES; SENSOR; CHEMOSENSORS; ZN2+; BIOLOGY; DESIGN; ZN(II); ION; RECOGNITION;
D O I：
10.1016/j.ica.2012.02.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two zinc(II) complexes, [Zn-2(II)(L-1)(2)] (1) and [Zn-2(II)(L-2)(2)] (2), and two cobalt(II) complexes, [Co-2(II)(L-1)(2)] (3) and [Co-2(II)(L-2)(2)] (4), (H2L1 = iminophenol derived from the condensation of 4-aminobenzylamine and salicyldehyde, H2L2 = Schiff-base of 4-aminobenzylamine and 3,5-di-tert-butylsalicyldehyde) supported by bis(N,O-bidentate) ligands have been synthesized and characterized. X-ray single crystal structures of 3 and 4 revealed the dimeric nature of the complexes with a 1:1 ratio of metal and ligand. The zinc(II) complexes have a very similar composition as established from different analytical and spectroscopic techniques. The iminophenols exhibit highly selective fluorescence enhancement with high quantum yield upon binding with Zn2+ in solution. A 50-fold enhancement of emission in zinc(II) complexes is observed with respect to free iminophenols. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：332 / 337
页数：6
相关论文
共 50 条
  • [31] Synthesis and structural characterization of zinc(II) and cobalt(II) complexes based on multidentate hydrazone ligands
    Li, Li
    Zhang, Yuan Zhuo
    Liu, E.
    Yang, Chengxiong
    Golen, James A.
    Rheingold, Arnold L.
    Zhang, Guoqi
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1110 : 180 - 184
  • [32] Synthesis and characterization of zinc(II) and cobalt(III) Schiff base complexes
    Hong, Sheng-Feng
    Liang, Xiao-Huan
    Fang, Hua-Cai
    Zhan, Xu-Lin
    Zhou, Zheng-Yuan
    Chen, Li
    Cai, Yue-Peng
    TRANSITION METAL CHEMISTRY, 2009, 34 (01) : 115 - 120
  • [33] Synthesis and characterization of zinc(II) and cobalt(III) Schiff base complexes
    Sheng-Feng Hong
    Xiao-Huan Liang
    Hua-Cai Fang
    Xu-Lin Zhan
    Zheng-Yuan Zhou
    Li Chen
    Yue-Peng Cai
    Transition Metal Chemistry, 2009, 34 : 115 - 120
  • [34] POLYMETALLIC COMPLEXES .7. BIS(BENZOIN)THIOCARBOHYDRAZIDE COMPLEXES OF COBALT(II), COPPER(II) AND ZINC(II)
    MAHAPATRA, BB
    PANDA, D
    TRANSITION METAL CHEMISTRY, 1984, 9 (12) : 476 - 478
  • [35] SYNTHESIS AND CHARACTERIZATION OF BIS(2-PYRIDYLMETHYL)AMINE COMPLEXES OF MANGANESE(II), ZINC(II), AND CADMIUM(II)
    GLERUP, J
    GOODSON, PA
    HODGSON, DJ
    MICHELSEN, K
    NIELSEN, KM
    WIEHE, H
    INORGANIC CHEMISTRY, 1992, 31 (22) : 4611 - 4616
  • [36] Synthesis, Characterization, and Reactivity Studies of Bis(β-diketiminate) Zinc(II) Complexes
    Rinke, Philipp
    Goerls, Helmar
    Kretschmer, Robert
    ISRAEL JOURNAL OF CHEMISTRY, 2023, 63 (7-8)
  • [37] Synthesis and Characterization of Iron(II), Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes Using Diphenylmethyl Xanthate Ligand
    Al-Fahdawi, Aeed S.
    Alsalihi, Eman I.
    ARO-THE SCIENTIFIC JOURNAL OF KOYA UNIVERSITY, 2018, 6 (01): : 33 - 37
  • [38] Synthesis and characterization of new Schiff bases and their cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II) and mercury(II) complexes
    Uçan, SY
    Uçan, M
    Mercimek, B
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2005, 35 (05) : 417 - 421
  • [39] SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF COBALT(II), NICKEL(II), ZINC(II), CADMIUM(II) AND MERCURY(II) WITH P-ACETAMIDOBENZALDEHYDE THIOSEMICARBAZONE
    KANAGARAJ, G
    RAO, GN
    POLYHEDRON, 1993, 12 (04) : 383 - 387
  • [40] SYNTHESIS AND CHARACTERIZATION OF MANGANESE(II), IRON(II), COBALT(II), NICKEL(II), COPPER(II), ZINC(II) AND CADMIUM(II) COMPLEXES WITH MACROCYCLIC AMIDOPHENOL
    SEVAGAPANDIAN, S
    VENKATACHALAM, KS
    ATHAPPAN, PR
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1995, 34 (06): : 487 - 489
12345