Growth of Metal-Free Carbon Nanotubes with an Amorphous Carbon Catalyst Layer

被引：1

作者：

Song, Woochang ^{[1
]}

Lim, Dong-Gun ^{[1
]}

Kim, Hee Dong ^{[2
]}

Lee, Jae-Hyeoung ^{[3
]}

Cha, Jaesang ^{[4
]}

Park, Gooman ^{[4
]}

Choi, Eun Chang ^{[5
]}

Hwang, Hyun Suk ^{[5
]}

Cho, Hyung Jun ^{[5
]}

Hong, Byungyou ^{[5
]}

Choi, Won Seok ^{[6
]}

机构：

[1] Chungju Natl Univ, Res Inst BINT New Technol, Chungju 380702, South Korea

[2] KEPCO Korea Elect Power Res Inst, Taejon 305380, South Korea

[3] Kunsan Natl Univ, Sch Elect & Informat Engn, Kunsan 573701, South Korea

[4] Seoul Natl Univ Technol, Dept Media Engn, Seoul 139743, South Korea

[5] Sungkyunkwan Univ, Sch Informat & Commun Engn, Suwon 440746, South Korea

[6] Hanbat Natl Univ, Dept Elect Engn, Taejon 305719, South Korea

来源：

JOURNAL OF THE KOREAN PHYSICAL SOCIETY | 2008年 / 53卷 / 04期

关键词：

Carbon nanotube (CNT); Amorphous carbon; Catalyst; Closed-field unbalanced magnetron (CFUBM); Microwave plasma-enhanced chemical-vapor deposition (MPECVD);

D O I：

10.3938/jkps.53.2142

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

An amorphous carbon (a-C) thin film was used as a catalyst, layer to grow metal-free carbon nanotubes (CNTs). The a-C films were deposited with a closed-field unbalanced magnetron (CFUBM) sputtering method on Si substrates. The CNTs were prepared using a microwave plasma-enhanced chemical-vapor deposition (MPECVD) method with an a-C catalyst film coated onto a silicon substrate by using methane (CH4) and hydrogen (H-2) gas. The CNTs were grown at different temperatures (550 degrees C, 650 degrees C and 750 degrees C) with other conditions being held constant. Field emission scanning electron microscopy (FE-SEM) images showed growth trend of the CNTs against temperature. High-resolution transmission electron microscopy (HR-TEM) images showed the CNTs to be multi-walled. Energy dispersive spectroscopy (EDS) measurements confirmed that the CNTs consisted solely of carbon.

引用

页码：2142 / 2146

页数：5

共 50 条

[21] Catalyst-free growth of carbon nanotubes by laser-annealing of amorphous SiC films
Botti, S
Asilyan, LS
Ciardi, R
Fabbri, F
Loreti, S
Santoni, A
Orlanducci, S
CHEMICAL PHYSICS LETTERS, 2004, 396 (1-3) : 1 - 5
[22] Metal-catalyst-free Growth and Characterization of Nitrogen-doped Carbon Nanotubes
Wang Can
Zhan Liang
Huang Zhen-Hong
Qiao Wen-Ming
Liang Xiao-Yi
Yang Jun-He
Ling Li-Cheng
JOURNAL OF INORGANIC MATERIALS, 2011, 26 (08) : 881 - 884
[23] Metal-catalyst-free growth of single-walled carbon nanotubes on substrates
Huang, Shaoming
Cai, Qiran
Chen, Jiangying
Qian, Yong
Zhang, Lijie
Journal of the American Chemical Society, 2009, 131 (06): : 2094 - 2095
[24] Metal-Catalyst-Free Growth of Single-Walled Carbon Nanotubes on Substrates
Huang, Shaoming
Cai, Qiran
Chen, Jiangying
Qian, Yong
Zhang, Lijie
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (06) : 2094 - +
[25] Exploring the barriers to metal-free carbon nanotube growth
Fort, Eric H.
Scott, Lawrence T.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[26] Metal-Free Catalyst for the Chemoselective Methylation of Amines Using Carbon Dioxide as a Carbon Source
Das, Shoubhik
Bobbink, Felix D.
Laurenczy, Gabor
Dyson, Paul J.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (47) : 12876 - 12879
[27] Evaluation of metal-free carbon nanotubes formed by SiC thermal decomposition
Harrison, Jeremy
Sambandam, Senthil N.
Boeckl, John J.
Mitchel, W. C.
Collins, W. E.
Lu, Weijie
JOURNAL OF APPLIED PHYSICS, 2007, 101 (10)
[28] Growth of carbon nanotubes on metal containing amorphous carbon (A-C:M) films
Yung, K. P.
Wei, J.
Tay, B. K.
PROCEEDINGS OF THE ASME INTERNATIONAL MECHANICAL ENGINEERING CONGRESS AND EXPOSITION 2007, VOL 5: ELECTRONICS AND PHOTONICS, 2008, : 43 - 46
[29] Mesoporous Carbon as a Metal-Free Catalyst for the Reduction of Nitroaromatics with Hydrazine Hydrate
Wang, Hui-Chun
Li, Bao-Lin
Zheng, Yan-Jun
Wang, Wen-Ying
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (09) : 2961 - 2965
[30] Ionic liquid in situ functionalized carbon nanotubes as metal-free catalyst for efficient electrocatalytic hydrogen evolution reaction
Li, Tianhao
Chen, Yanping
Hu, Weihua
Yuan, Weiyong
Zhao, Qichao
Yao, Yanling
Zhang, Bing
Qiu, Chuntian
Li, Chang Ming
NANOSCALE, 2021, 13 (08) : 4444 - 4450

← 1 2 3 4 5 →