A mathematical model of stress generation and fracture in lithium manganese oxide

被引：344
|
作者：
Christensen, J [1 ]
Newman, J [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2006年 / 153卷 / 06期
关键词：
D O I：
10.1149/1.2185287
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Fracture of LiyMn2O4 is predicted with a numerical model that calculates the stress generated in spherical particles due to lithium intercalation along the 4-V plateau and phase change along the 3-V plateau. In the former case, fracture is probable at the rates typical of high-power applications, while in the latter case, the probability of fracture is linked not to the discharge rate or particle size, but to the LiMn2O4/Li2Mn2O4 phase ratio. The two-phase material should fracture immediately upon lithium extraction. The effects of variation in thermodynamic factor, diffusion coefficient, and lattice parameter are examined in detail. (C) 2006 The Electrochemical Society.
引用
收藏
页码：A1019 / A1030
页数：12
相关论文
共 50 条
  • [31] Electrical and ESR studies of lithium manganese oxide spinels
    Julien, C
    Gendron, F
    Ziolkiewicz, S
    Nazri, GA
    [J]. SOLID STATE IONICS V, 1999, 548 : 187 - 195
  • [32] Electrochemical characterization of commercial lithium manganese oxide powders
    Huang, H
    Chen, CH
    Perego, RC
    Kelder, EM
    Chen, L
    Schoonman, J
    Weydanz, WJ
    Nielsen, DW
    [J]. SOLID STATE IONICS, 2000, 127 (1-2) : 31 - 42
  • [33] Simulation of the surface structure of lithium manganese oxide spinel
    Benedek, R.
    Thackeray, M. M.
    [J]. PHYSICAL REVIEW B, 2011, 83 (19)
  • [34] Performances of lithium manganese oxide prepared by hydrothermal process
    Kong Long
    Li Yun-jiao
    Zhang Peng
    Huang Hai-hua
    Ye Wang-qi
    Li Chun-xia
    [J]. JOURNAL OF CENTRAL SOUTH UNIVERSITY, 2014, 21 (04) : 1279 - 1284
  • [35] Synthesis of birnessite-type lithium manganese oxide
    Feng, Q
    Yanagisawa, K
    Yamasaki, N
    [J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1996, 104 (09) : 897 - 899
  • [36] Amorphous manganese oxide cathodes for rechargeable lithium batteries
    Im, D
    Manthiram, A
    [J]. MATERIALS FOR ELECTROCHEMICAL ENERGY CONVERSION AND STORAGE, 2002, 127 : 205 - 214
  • [37] Electrochemical Stiffness Changes in Lithium Manganese Oxide Electrodes
    Capraz, Omer Ozgur
    Bassett, Kimberly L.
    Gewirth, Andrew A.
    Sottos, Nancy R.
    [J]. ADVANCED ENERGY MATERIALS, 2017, 7 (07)
  • [38] RECOVERY OF LITHIUM FROM SEAWATER BY MANGANESE OXIDE ADSORBENT
    OOI, K
    MIYAI, Y
    KATOH, S
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 1986, 21 (08) : 755 - 766
  • [39] Study of structural and electrochemical characteristics of lithium manganese oxide
    Smirnov, S.E.
    Zhorin, V.A.
    Sivtsov, A.V.
    Yashtulov, N.A.
    Ogorodnikov, A.A.
    [J]. 2003, Maik Nauka (39):
  • [40] Lithiated manganese oxide cathodes for rechargeable lithium batteries
    Abraham, KM
    Pasquariello, DM
    Nguyen, TH
    Jiang, Z
    Peramunage, D
    [J]. ELEVENTH ANNUAL BATTERY CONFERENCE ON APPLICATIONS AND ADVANCES, 1996, : 317 - 323
12345